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How to make bright quantum dots even brighter

How to make bright quantum dots even brighter
To make a quantum dot consisting of a perovskite nanocrystal (left) more efficient, researchers have created special molecules (right) that form a protective layer around the quantum dot. Credit: Kovalenko Lab

Quantum dots are a kind of artificial atom: just a few nanometers in size and made of semiconductor materials, they can emit light of a specific color or even single photons, which is important for quantum technologies. The discoverers and pioneers of the commercial production of quantum dots were awarded the Nobel Prize in Chemistry in 2023.

In recent years, quantum dots made of perovskites have attracted particular attention. Perovskites belong to a class of materials that have a similar structure to the mineral perovskite (calcium titanate). Quantum dots made of such materials were produced for the first time by ETH Zurich in 2015.

These quantum dots made of can be mixed with liquids to form a dispersion, which makes them easy to process further. Moreover, their special optical properties make them shine more brightly than many other quantum dots. They can also be produced more cheaply, which makes them interesting for applications in displays, for instance.

A team of researchers led by Maksym Kovalenko at ETH Zurich and Empa, working in collaboration with counterparts in Ukraine and the U.S., have now demonstrated how these promising properties of perovskite quantum dots can be improved further. They used chemical methods for and quantum mechanical effects that had never before been observed in perovskite quantum dots. The researchers recently published their results in two papers in Nature.

How to make bright quantum dots even brighter
The phospholipid molecules designed by the ETH researchers create a protective layer around the perovskite nanocrystal and make it possible to disperse it in non-aqueous solutions. They also ensure that the quantum dot emits photons more continuously. Credit: Kovalenko Lab

Unhappy atoms reduce brightness

Brightness is an important measure for quantum dots and is related to the number of photons the quantum dot emits per second. Quantum dots radiate photons of a specific color (and hence frequency) after being excited, for example, by ultraviolet light of a higher frequency.

This leads to the formation of an exciton consisting of an electron, which can now move more freely, and a hole—in other words, a missing electron—in the energetic band structure of the material. The excited electron can fall back to a lower energy state and thus recombine with the hole. If the energy released during this process is converted into a photon, the quantum dot emits light.

This doesn't always work, however. "At the surface of the perovskite nanocrystals are 'unhappy' atoms that are missing a neighbor in the ," senior researcher Gabriele Raino explains. These edge atoms disturb the balance between positive and negative charge carriers inside the nanocrystal and can cause the energy released during a recombination to be converted into lattice vibrations instead of being emitted as light. As a result, the quantum dot "blinks," meaning that it doesn't shine continuously.

Protective coating made of phospholipids

To prevent this from happening, Kovalenko and his team have developed tailor-made molecules known as phospholipids. "These phospholipids are very similar to the liposomes in which, for instance, the mRNA vaccine against the coronavirus is embedded in such a way as to make it stable in the bloodstream until it reaches the cells," Kovalenko explains.

An important difference: the researchers optimized their molecules so that the polar (electrically sensitive) part of the molecule latches onto the surface of the perovskite quantum dots and makes sure that the "unhappy" atoms are provided with a charge partner.

The nonpolar part of the phospholipid that protrudes on the outside also makes it possible to turn quantum dots into a dispersion inside non-aqueous solutions such as organic solvents. The lipid coating on the surface of the perovskite nanocrystals is also important for their , as Kovalenko emphasizes: "This surface treatment is absolutely essentially for anything we might want to do with the quantum dots."

So far, Kovalenko and his team have demonstrated the treatment for quantum dots made of lead halide perovskites, but it can also be easily adapted to other metal halide quantum dots.

How to make bright quantum dots even brighter
The phospholipid molecules designed by the ETH researchers create a protective layer around the perovskite nanocrystal and make it possible to disperse it in non-aqueous solutions. They also ensure that the quantum dot emits photons more continuously. Credit: Kovalenko Lab

Even brighter thanks to superradiance

With the lipid surface it was possible to reduce the blinking of the quantum dots to such an extent to emit a photon in 95% of electron-hole recombination events. To make the quantum dot even brighter, however, the researchers had to increase the speed of the recombination itself—and that requires quantum mechanics.

An excited state, such as an exciton, decays when a dipole—positive and negative charges displace with respect to each other—interacts with the electromagnetic field of the vacuum. The larger the dipole, the faster the decay. One possibility of creating a larger dipole involves coherently coupling several smaller dipoles to each other. This can be compared to pendulum clocks that are mechanically connected and tick in step with each other after a certain length of time.

The researchers were able to show experimentally that the coherent coupling also works in perovskite quantum dots—with only a single exciton dipole that—through quantum mechanical effects—spreads out all over the volume of the quantum dot, thereby creating several copies of itself, as it were. The larger the quantum dot, the more copies can be created. These copies can bring about an effect known as superradiance, by which the exciton recombines much faster.

The quantum dot is consequently also ready more quickly to take up a new exciton and can thus emit more photons per second, making it even brighter. An important detail to note is that the faster quantum dot continues to emit (not several photons at once), which makes it suitable for .

The improved perovskite are not only of interest for light production and displays, says Kovalenko, but also in other less obvious fields. For instance, they could be used as light-activated catalysts in organic chemistry. Kovalenko is conducting research into such applications and several others, including within the framework of NCCR Catalysis.

More information: Chenglian Zhu et al, Single-photon superradiance in individual caesium lead halide quantum dots, Nature (2024). DOI: 10.1038/s41586-023-07001-8.

Viktoriia Morad et al, Designer Phospholipid Capping Ligands for Soft Metal Halide Nanocrystals, Nature (2023). DOI: 10.1038/s41586-023-06932-6

Journal information: Nature

Provided by ETH Zurich

Citation: How to make bright quantum dots even brighter (2024, January 31) retrieved 23 February 2024 from
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