Air pollution may increase freezing rain in northern hemisphere

Freezing rain is a typical weather disaster in winter and early spring over many regions of the world, even tropical areas. It develops as supercooled water (below 0 °C) in the air and freezes immediately after depositing on cold surfaces. In southern China, freezing rain mainly happens in the mountainous areas.

Now, researchers from the Institute of Atmospheric Physics of Chinese Academy of Sciences have found that air pollution may increase freezing rain in the northern hemisphere.

Their findings were published in Atmospheric Environment.

The nature of freezing rain is that raindrops stay supercooled in the atmosphere below 0 °C. Previous studies have attributed the presence of supercooled drops in the atmosphere to the lack of ice nuclei. In fact, this is not the case, because ice nuclei remain in supercooled drops when snow melts and forms these drops in even higher and warmer conditions.

Laboratory experiments have found that elevated soluble chemicals help the drops stay supercooled, and this chemical effect, known as freezing point depression, is also reproduced by numerical models. However, there is no evidence from field observations that the effect of freezing point depression exists in the precipitation.

Since 2015, Drs. Li Xingyu and Pan Yuepeng from IAP have been conducting a long-term measurement of the physical and chemical composition of freezing rain at Mount Heng, which lies in south-central China at 27°18′6″N, 112°41′5″E. The elevation of the sampling site is 1265.9 m, above the top of the atmospheric boundary layer, with temperature near 0 °C in winter favoring the occurrence of supercooled fog and freezing rain. This sampling site has also recorded the record icing thickness in China. According to the first seven-year observations, the freezing rain at Mount Heng was found to be acidic (pH < 5) with higher concentrations of soluble ions and organics than those in rain.

The team also worked with climatologists at universities and research institutes in Canada and China to explore the formation mechanisms of freezing rain and their trends in the future. They found that as the concentrations of soluble ions (especially ammonium nitrate) increase, the ambient temperatures of freezing rain show decreasing trends.

"This study presented the first chemical view on freezing rain, a physical phenomenon in traditional belief," says Prof. Ronald Stewart at the University of Manitoba of Canada, a coauthor of the study. "The higher ionic concentration may depress the temperature needed to freeze raindrops and this process prolongs the existence of freezing rain."

"Against the background of global warming, the influencing area of the freezing rain will shift northward, and the effect of freezing point depression induced by air pollution in northern China may be amplified," said Dr. Zhu Xiaying at the National Climate Center, another coauthor of the study.