Research group isolates reaction step that describes energetics of catalysis on materials

water molecule
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New research published in Nature Materials from Associate Professor Tanja Cuk and colleagues sheds light on a fundamental chemical reaction—the breaking apart of water to produce a molecular fuel such as hydrogen. Cuk is faculty in the University of Colorado Boulder Department of Chemistry and the Materials Science and Engineering Program (MSE) and is a Fellow in the Renewable and Sustainable Energy Institute (RASEI).

When undergoes such a , there are a number of discrete reaction steps that should occur in sequence. Cuk's lab specializes in timing these steps and therefore isolating individual reactions as part of the broader process.

"This paper isolated one of the reaction steps in time, so we can then learn more about the energetics of that discrete step—how strong or weak the bonds are before and after it—within the broader reaction," Cuk said.

Understanding the needed to form a chemical is key to its usefulness as a fuel source. If an element has weak electrochemical bonds, it has a high- potential, because it can be broken apart easily.

"Similar to what plants do naturally, we are trying to break the bonds of water and reform the bonds of oxygen," Cuk said. "The protons left over create for fuel."

Cuk and her group used a pulsing to generate current and a tuning of the water's pH to get more products of the first step—reaction intermediates—with higher pH. This creates a curve from which the free energy change of that reaction step can be determined.

"The electrochemical reaction was driven by the charge," Cuk said. "We have an electrode and we shine light on it. That is the energy inputted into the whole reaction. But we shine pulsed light, so we can time the separate reaction steps within the total fuel-producing reaction."

Because sunlight is continuous, it can obscure the individual steps associated with a chemical reaction. Using pulsed light in principle allows the researchers to experimentally determine the free energy needed for each meta-stable reaction step. However, a pulsed light , usually called pump-probe or time-resolved spectroscopy, had yet to live up to this.

This work experimentally determined the free energy change of the first electron and proton transfer from water at a material surface. This understanding is especially important for materials science because theorists use it to differentiate the activity of water splitting catalysts. If this is a difficult, energy-intensive process, the catalyst is not as efficient at producing the final fuel, hydrogen.

Ilya Vinogradov, a postdoctoral researcher in the Cuk Research Group and with RASEI, contributed to building the transient reflectance setup, wrote new data acquisition software and mentored the graduate students in data acquisition and analysis. MSE graduate students Suryansh Suryansh and Hanna Lyle acquired the data and processed the data sets. Michael Paolino, a graduate student in physics, aided in the latest data collection. Vinogradov furthered the SVD analysis spearheaded by research associate Aritra Mandal and contributed to the rotation analysis described in the paper.

"This research is impactful because it provides an experimental measure of an important theoretical materials performance predictor—free energy change of the first electron transfer step—for water splitting catalysis," Vinogradov said. "If a material's descriptor correlates well with device performance, one can computationally optimize its chemical composition and crystal structure for the descriptor in lieu of directly measuring the device's performance."

This allows researchers to evaluate different materials as high performers more efficiently and quickly, saving time and cost for materials that would otherwise need to be subject to experimentation.

"Although our method is not quite there yet in terms of throughput and precision, one way a more solid experimental footing may help improve the materials design strategy is by discovering non-idealities that the theorists may have missed," Vinogradov said. "This can help improve the descriptor's predictive accuracy."

Cuk said some of these non-idealities would have to do with the , or the timing with which the intermediate products turn over, rather than directly with the free energies of each reaction step.

"This is important for a truly sustainable energy storage cycle, where the rate at which products turnover keeps up with the rate at which rays of sunlight come in," she said. "By using a time-resolved spectroscopy, we can get at both the free energies and the rates that circumscribe fuel production."

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More information: Ilya Vinogradov et al, Free energy difference to create the M-OH* intermediate of the oxygen evolution reaction by time-resolved optical spectroscopy, Nature Materials (2021). DOI: 10.1038/s41563-021-01118-9
Journal information: Nature Materials

Citation: Research group isolates reaction step that describes energetics of catalysis on materials (2021, December 16) retrieved 24 May 2022 from
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