A chemical embrace from the perfect host

A chemical embrace from the perfect host
Gengwu Zhang performs the separation experiment using two extraction towers. Credit: © 2020 KAUST

An industrial process that currently consumes vast amounts of energy in petrochemical plants around the globe could be replaced by an alternative process so efficient that it requires no heating or elevated pressure.

Niveen Khashab from KAUST's Advanced Membranes and Porous Materials Center and her colleagues have developed a new way to separate derivates of benzene called xylenes.

"Discussions with industry to implement the technology are already underway," Khashab says.

Xylenes come in three different forms, known as , which differ from each other only in the location of a single carbon atom. Xylenes are used in many large-scale applications, including in polymers, plastics and fibers, and as fuel additives, but many uses rely on just one of the three isomers. Because the isomers are so similar, their , such as boiling point, are very close, which makes separating them energetically expensive.

"Every year, the global energy costs of separating these isomers using distillation is about 50 gigawatts, enough to power roughly 40 million homes," says Gengwu Zhang, a postdoc in Khashab's team and first author of the study. "We wanted to develop a method with and low energy consumption to separate and purify these isomers for the ."

KAUST chemists are developing a separation method for the petrochemical industry with high efficiency and low energy consumption. Credit: © 2020 KAUST; Heno Hwang

To draw apart the isomers, Khashab and her team used doughnut-shaped molecules called cucurbiturils. The hole in the middle of these molecules can host smaller molecules inside it. The hole in the middle of cucurbit[7]uril is the ideal size for hosting the ortho-isomer of xylene, the team showed. Using a process called , the team used cucurbit[7]uril to separate ortho-xylene from the other isomers. "We could separate ortho-xylene with more than 92 percent specificity after one extraction cycle," Zhang says. "Unlike previous methods, our method is performed under ambient temperature and pressure, which means very low energy consumption and easy operation," he adds.

The whole process was designed to be readily adopted in the existing plants of petrochemical companies, Khashab explains. "Liquid-liquid extraction towers are already used in industry and so it is relatively easy to incorporate our material in this setup," she says. In addition, cucurbit[7]uril is inexpensive, commercially available or easily made, and highly stable compared to most porous materials.

"We have already shown that we can separate xylene from commercial oil samples at scales of up to 0.5 liters," Khashab adds. "We are in touch with Saudi Aramco to take this process to industrial implementation."

The team is also examining other applications for this separation process, Zhang says.

The study is published in the journal Chem.

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More information: Gengwu Zhang et al. Shape-Induced Selective Separation of Ortho-substituted Benzene Isomers Enabled by Cucurbit[7]uril Host Macrocycles, Chem (2020). DOI: 10.1016/j.chempr.2020.03.003
Journal information: Chem

Citation: A chemical embrace from the perfect host (2020, March 30) retrieved 7 May 2021 from https://phys.org/news/2020-03-chemical-embrace-host.html
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