A new light on significantly faster computer memory devices

November 30, 2018, Arizona State University
Exponential decay of the ISF and the a-relaxation time ta for liquid Ge1Sb2Te4 above Tm. (A) The decay of the ISF S(q,t) of liquid Ge1Sb2Te4 at the structure factor first maximum q0 = 2.0 Å−1 measured at temperatures above Tm = 903 K. The data, typical of high-fluidity systems, are best fitted by simple exponential functions (solid lines), each yielding a single relaxation time ta (see the main text for details). Note that at a very short time (<0.65 ps), the data points correspond to phonons and fast processes that are not explicitly taken into account in the fitting. This is consistent with the analysis of the dynamic structure factor S(q,w) in the energy transfer (ħw) domain (see fig. S1), where S(q,w) is best described by a single Lorentzian form. (B) Arrhenius plot for the a-relaxation time ta above Tm. Credit: Science Advances (2018). http://advances.sciencemag.org/content/4/11/eaat8632

A team of scientists from Arizona State University's School of Molecular Sciences and Germany have published in Science Advances online today an explanation of how a particular phase-change memory (PCM) material can work one thousand times faster than current flash computer memory, while being significantly more durable with respect to the number of daily read-writes.

PCMs are a form of computer random-access memory (RAM) that store data by altering the state of the matter of the "bits", (millions of which make up the device) between liquid, glass and crystal . PCM technology has the potential to provide inexpensive, high-speed, high-density, high-volume, nonvolatile storage on an unprecedented scale.

The basic idea and material were invented by Stanford Ovshinsky, long ago, in1975, but applications have lingered due to lack of clarity about how the material can execute the phase changes on such short time scales and technical problems related to controlling the changes with necessary precision. Now high tech companies like Samsung, IBM and Intel are racing to perfect it.

The semi-metallic material under current study is an alloy of germanium, antimony and tellurium in the ratio of 1:2:4. In this work the team probes the microscopic dynamics in the liquid state of this PCM using quasi-elastic neutron scattering (QENS) for clues as to what might make the phase changes so sharp and reproducible.

On command, the structure of each microscopic bit of this PCM material can be made to change from glass to crystal or from crystal back to glass (through the liquid intermediate) on the time scale of a thousandth of a millionth of a second just by a controlled heat or light pulse, the former now being preferred. In the amorphous or disordered phase, the material has high electrical resistance, the "off" state; in the crystalline or ordered phase, its resistance is reduced 1000 fold or more to give the "on" state.

These elements are arranged in two dimensional layers between activating electrodes, which can be stacked to give a three dimension array with particularly high active site density making it possible for the PCM device to function many times faster than conventional flash memory, while using less power.

"The amorphous phases of this kind of material can be regarded as "semi-metallic glasses"," explains Shuai Wei, who at the time was conducting postdoctoral research in SMS Regents' Professor Austen Angell's lab, as a Humboldt Foundation Fellowship recipient.

"Contrary to the strategy in the research field of "metallic glasses", where people have made efforts for decades to slow down the crystallization in order to obtain the bulk glass, here we want those semi-metallic glasses to crystallize as fast as possible in the liquid, but to stay as stable as possible when in the glass state. I think now we have a promising new understanding of how this is achieved in the PCMs under study."

A Deviation from the expected

Over a century ago, Einstein wrote in his Ph.D. thesis that the diffusion of particles undergoing Brownian motion could be understood if the frictional force retarding the motion of a particle was that derived by Stokes for a round ball falling through a jar of honey. The simple equation: D (diffusivity) = kBT/6??r where T is the temperature, ? is the viscosity and r is the particle radius, implies that the product D?/T should be constant as T changes, and the surprising thing is that this seems to be true not only for Brownian motion, but also for simple molecular liquids whose molecular motion is known to be anything but that of a ball falling through honey!

"We don't have any good explanation of why it works so well, even in the highly viscous supercooled state of molecular liquids until approaching the , but we do know that there are a few interesting liquids in which it fails badly even above the melting point," observes Angell.

"One of them is liquid tellurium, a key element of the PCM materials. Another is water which is famous for its anomalies, and a third is germanium, a second of the three elements of the GST type of PCM. Now we are adding a fourth, the GST liquid itself..!!! thanks to the neutron scattering studies proposed and executed by Shuai Wei and his German colleagues, Zach Evenson (Technical University of Munich, Germany) and Moritz Stolpe (Saarland University, Germany) on samples prepared by Shuai with the help of Pierre Lucas (University of Arizona)."

Another feature in common for this small group of liquids is the existence of a maximum in liquid density which is famous for the case of water. A density maximum closely followed, during cooling, by a metal-to semiconductor transition is also seen in the stable liquid state of arsenic telluride, (As2Te3), which is first cousin to the antimony telluride (Sb2Te3 ) component of the PCMs all of which lie on the "Ovshinsky" line connecting antimony telluride (Sb2Te3 ) to germanium telluride (GeTe) in the three component phase diagram. Can it be that the underlying physics of these liquids has a common basis?

It is the suggestion of Wei and coauthors that when germanium, antimony and tellurium are mixed together in the ratio of 1:2:4, (or others along Ovshinsky's "magic" line) both the density maxima and the associated metal to non-metal transitions are pushed below the melting point and, concomitantly, the transition becomes much sharper than in other chalcogenide mixtures.

Then, as in the much-studied case of supercooled water, the fluctuations associated with the response function extrema should give rise to extremely rapid crystallization kinetics. In all cases, the high temperature state (now the metallic state), is the denser.

"This would explain a lot," enthuses Angell "Above the transition the liquid is very fluid and crystallization is extremely rapid, while below the transition the liquid stiffens up quickly and retains the amorphous, low-conductivity state down to room temperature. In nanoscopic "bits", it then remains indefinitely stable until instructed by a computer-programmed heat pulse to rise instantly to a temperature where, on a nano-second time scale, it flash crystallizes to the conducting state, the "on" state.

Lindsay Greer at Cambridge University has made the same argument couched in terms of a "fragile-to-strong" liquid transition".

A second slightly larger heat pulse can take the "bit" instantaneously above its and then, with no further heat input and close contact with a cold substrate, it quenches at a rate sufficient to avoid crystallization and is trapped in the semi-conducting state, the "off" state.

"The high resolution of the neutron time of flight-spectrometer from the Technical University of Munich was necessary to see the details of the atomic movements. Neutron scattering at the Heinz Maier-Leibnitz Zentrum in Garching is the ideal method to make these movements visible," states Zach Evenson.

Explore further: Understanding how electrons turn to glass

More information: "Breakdown of the Stokes-Einstein relation above the melting temperature in a liquid phase-change material" Science Advances (2018). advances.sciencemag.org/content/4/11/eaat8632

Related Stories

Understanding how electrons turn to glass

October 24, 2017

Researchers at Tohoku University have gained new insight into the electronic processes that guide the transformation of liquids into a solid crystalline or glassy state.

Making steps toward improved data storage

November 7, 2018

A team of scientists has created the world's most powerful electromagnetic pulses in the terahertz range to control in fine detail how a data-storage material switches physical form. This discovery could contribute to scaled-down ...

The '50-50' chip: Memory device of the future?

September 13, 2013

A new, environmentally-friendly electronic alloy consisting of 50 aluminum atoms bound to 50 atoms of antimony may be promising for building next-generation "phase-change" memory devices, which may be the data-storage technology ...

Structural origin of glass transition

June 23, 2015

A University of Tokyo research group has demonstrated through computer simulations that the enhancement of fluctuations in a liquid's structure plays an important role as a liquid becomes a solid near the glass-transition ...

Recommended for you

Tangled magnetic fields power cosmic particle accelerators

December 13, 2018

Magnetic field lines tangled like spaghetti in a bowl might be behind the most powerful particle accelerators in the universe. That's the result of a new computational study by researchers from the Department of Energy's ...

Stretched quantum magnetism uncovered by quantum simulation

December 13, 2018

By studying ultracold atoms trapped in artificial crystals of light, Guillaume Salomon, a postdoc at the Max-Planck-Institute of Quantum Optics and a team of scientists have been able to directly observe a fundamental effect ...

The secret life of cloud droplets

December 13, 2018

Do water droplets cluster inside clouds? Researchers confirm two decades of theory with an airborne imaging instrument.

7 comments

Adjust slider to filter visible comments by rank

Display comments: newest first

Eikka
5 / 5 (1) Nov 30, 2018
Technically speaking, the high speed of today's DRAM is due to clever tricks of interleaving memory access. The actual RAM chip runs at a fraction of the speed of the memory bus, and the data throughput is achieved by accessing different parts of memory in clever patterns. Accessing the same memory cell repeatedly takes forever (CAS latency)

The original SDRAM memory back in the 90's running at 100 MHz could access a word of memory in 20 nanoseconds. The latest DDR4 memory can access it in around 10 nanoseconds, even though the command frequency has increased to 1800 MHz. RAM is actually very very slow, and hasn't improved much in the last 20 years.

That's a major impediment to computer performance - random access to data is really slow and cache misses carry a terrible penalty. You can stream gigabytes per second, if you already know which data you want, but if you need to do something smart like branching your code, it all goes down the toilet.

PCM is even slower.
Eikka
5 / 5 (1) Nov 30, 2018
For the same reason, things like GPUs and the shader algoritms which run on them, which really need fast memory access, are really inefficient in how they use RAM. They have multiple copies of the same data in different parts of memory just so they could pull a copy as soon as possible without waiting for the previously accessed memory cells to recharge.
Da Schneib
not rated yet Nov 30, 2018
@Eikka, I agree with your assessment that this is not ground-breaking memory technology. There are, however, such technologies that have been proven in the lab; when they will emerge into real technology is difficult to assess when more tricks like this one keep showing up and brain-dead marketing drones keep succeeding in convincing management to put money into tricks and not into truly ground-breaking technology.

A board is long and hard and made of wood.
Amy25
5 / 5 (2) Dec 01, 2018
Amazing to read "the structure of each microscopic bit of this PCM material can be made to change from glass to crystal or from crystal back to glass (through the liquid intermediate) on the time scale of a thousandth of a millionth of a second just by a controlled heat or light pulse, the former now being preferred. In the amorphous or disordered phase, the material has high electrical resistance, the "off" state; in the crystalline or ordered phase, its resistance is reduced 1000 fold or more to give the "on" state" nice article.
Thorium Boy
1 / 5 (2) Dec 01, 2018
Remember germanium circuits? Never happened. Then optical computing. Didn't happen. Quantum computing. Didn't happen. Still, the happy new stories continue about potential radical breakthroughs.
Parsec
5 / 5 (1) Dec 01, 2018
@Eikka - there are actually a variety of memory types in use today. The kind you are referencing use cells based on tiny capacitors, and are only capable of holding onto their contents for a few hundred microseconds. That is why they need to be refreshed, or read and rewritten every 100 microseconds or so.

But there are other types of memory based on flip flops that are much faster, and capable of holding onto their contents as long as power flows (no refresh needed). The problem is that each cell is a lot larger (it takes more transistors to make them work) and consume a lot more power. The fact that this new material is capable of holding onto its memory contents without needing refresh, and the size of the cells is small because only a single driver transistor is required, combined with the fast read/write access time of the new material, is truly a game changer.
PPihkala
5 / 5 (1) Dec 01, 2018
PCM is not so much a replacement for DRAM than for Flash. Flash is much slower than DRAM, but is needed for non-volatile data. So huge PCM memories are meant to replace Flash and hard disk drives. Assuming of course that PCM will be better than those, in terms of space, speed, price and consumed electricity.

Please sign in to add a comment. Registration is free, and takes less than a minute. Read more

Click here to reset your password.
Sign in to get notified via email when new comments are made.