Gecko inspired adhesive can attach and detach using UV light

January 19, 2017 by Bob Yirka, Phys.org report
The azobenzene molecular structure re-configures when exposed to UV light, bending the sticky structure until attached items fall off. Credit: Emre Kizilkan and Jan Strueben

(Phys.org)—A small team of researchers at Kiel University in Germany has developed new technology that emulates the way a gecko uses its toes to cling to flat surfaces. In their paper published in the journal Science Robotics, the team describes their new adhesive, how well it works and possible applications.

Geckos are famous for their ability to walk up such as glass with little apparent effort—this ability has fascinated scientists for many years, inciting some to attempt to replicate the ability with various sticky-type materials. To date, there has been some success but most techniques require the use of heat or electronics to get the materials to adhere and let go on demand. In this new effort, the researchers report on a type of adhesive that can be switched on and off simply by shining a UV light on it.

The adhesive is a three-layer tape—on top are mushroom-shaped pillars with sticky flat tops that actually touch the surface of the target material, i.e., glass. The pillars are embedded in a layer of polydimethylsiloxane, which is in turn connected to a layer of azobenzene liquid crystals. At the bottom, there is another layer of polydimethylsiloxane. The adhesive works because the azobenzene crystals are sensitive to UV light—they change position relative to one another when a UV light is aimed at them. The upper material allows the adhesive to stick to a glass surface, but only when it is aligned properly, which happens in the absence of UV light. Aiming a UV light at the adhesive causes it to curl slightly pulling the sticky parts from the glass surface, allowing the adhesive to release. Varying the amounts of UV applied allows for tuning the degree of adherence required.

Directed by leg movement, gecko toes have the remarkable ability to stick and unstick quickly and easily. Credit: Stanislav N. Gorb

The team tested their adhesive by causing it to cling to and release from glass spheres, slides and even Eppendorf tubes, which they note are much larger than the adhesive used to hold them. They suggest it might be possible to hoist objects as heavy as a human being.

The researchers suggest their adhesive, which they have named bioinspired photocontrollable microstructured transport device, might have industrial applications such as moving slides, test tubes or even electronic pieces. Besides the advantage of not requiring heat, the also leaves no residue, ensuring a clean working environment.

Inspired from gecko toes, these cylindrical microstickers have a remarkable ability to “switch off” stickiness when flashed with UV light. Credit: Carla Schaffer / AAAS

These microstickers look like mushroom-shaped pillars. Credit: Emre Kizilkan
When illuminated with UV light, the intelligent material with the adhesive surface bends. This way it can lift, transport and put down flat and three-dimensional objects (here, a 1 millimetre diameter glass sphere). Credit: Emre Kizilkan

Explore further: Dry adhesive holds in extreme cold, strengthens in extreme heat

More information: Emre Kizilkan et al. Bioinspired photocontrollable microstructured transport device, Science Robotics (2017). DOI: 10.1126/scirobotics.aak9454

Abstract
Geckos, which can walk upside down on vertical and underneath horizontal surfaces, owe this ability to the hierarchical structures under their toes. These structures are responsible for substantial adhesion and, at the same time, for quick detachment by mechanical stimulus through leg movements. Inspired by such stimuli-responsive systems in nature, we developed an artificial, photocontrollable microstructured transport device. Through tunable ultraviolet light illumination, the adhesive ability of this bioinspired transport device is reduced up to a factor of 2.7 in terms of adhesive forces and is quickly recovered when the light stimulus ceases. This bioinspired photocontrollable device has been used in a pick-up and drop-down system for transporting planar and three-dimensional solid objects.

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