Physicists find unusual electronic properties in bismuth-based crystalline material

Feb 19, 2009

Physicists at Rutgers University have discovered unusual electronic properties in a material that has potential to improve solar cell efficiency and computer chip design.

The scientists determined that a crystal made of bismuth, iron and oxygen can perform an electronic feat typically not feasible with conventional semiconductors. It acts as a reversible diode - essentially an electronic turnstile that lets current flow in one direction under certain conditions and in the opposite direction under different conditions. Traditional semiconductor diodes are not reversible - the direction of current flow that they allow is fixed during fabrication.

The researchers reported their findings today in a paper published in Science Express, an advance web posting of papers to be published in upcoming issues of the journal Science.

The scientists also discovered that diodes made from this material generate current when light falls on them, making the material a potential candidate for future solar cells. The material appears very sensitive to light at the blue end of the spectrum, a property that has the potential to increase solar cell efficiency.

"We've reached the upper limit of efficiency with today's solar cells," said Sang-Wook Cheong, physics professor in the School of Arts and Sciences and one of the paper's five authors. "While we still don't know how efficiently this material will ultimately perform as a solar cell, we do need to keep investigating alternate technologies that show potential for improvement."

The crystal that Cheong and his colleagues investigated is a ferroelectric material, meaning that the crystal exhibits electrical polarization, or alignment. This polarization, which the scientists believe controls the crystal's ability to act as a diode, is known as a "bulk effect" - a characteristic that permeates the whole crystal. In contrast, traditional semiconductors act as diodes based on electrical effects at the interfaces between two different materials.

By applying an external voltage on the ferroelectric crystal, the polarization of the material reverses, along with the direction that the diode allows electricity to flow.

"This could make computer chip designs more flexible," said Cheong. "Engineers could design a single circuit element that performs one task under a certain configuration and another task under a different configuration."

The material belongs to class of crystalline materials known as perovskites, which have two positive ions of very different atomic sizes (in this case, bismuth and iron) bound to negative ions (in this case, oxygen). It has three oxygen atoms for each bismuth and iron atom.

Source: Rutgers University

Explore further: X-ray powder diffraction beamline at NSLS-II takes first beam and first data

add to favorites email to friend print save as pdf

Related Stories

New materials for more powerful solar cells

Nov 12, 2014

Applying a thin film of metallic oxide significantly boosts the performance of solar panel cells—as recently demonstrated by Professor Federico Rosei and his team at the Énergie Matériaux Télécommunications Research ...

Recommended for you

Particles, waves and ants

Nov 26, 2014

Animals looking for food or light waves moving through turbid media – astonishing similarities have now been found between completely different phenomena.

User comments : 0

Please sign in to add a comment. Registration is free, and takes less than a minute. Read more

Click here to reset your password.
Sign in to get notified via email when new comments are made.