Five ways to turn carbon dioxide from pollution to a valuable product

Five ways to turn CO2 from pollution to a valuable product
Creating a commodity out of carbon could help kickstart its removal from the atmosphere. Credit: Elevate on Unsplash/Shutterstock

It's far easier to avoid burning fossil fuels than it is to clean up CO2 emissions once they're in the Earth's atmosphere. But the world no longer has the luxury of choice—drastic emission reductions and rapid CO2 removal and storage will both be necessary to avoid the worst impacts of global heating.

What if, instead of wasting all that CO2, it could be turned into something useful? There's currently little economic incentive for industries that emit CO2 to capture it, let alone to draw it directly down from the atmosphere. Identifying valuable products and how to make them might kickstart CO2 removal on an industrial scale, and help bring down emissions in the process. In our recent paper, we set out to clarify what these processes and products might be.

We considered processes that use CO2 captured from industrial emissions, and also biological processes that can directly draw down CO2 from the air. We projected that between one and ten gigatons of CO2 could be utilized per year by 2050, at costs of under USD$100 (£77) per ton of CO2. Humans currently emit 37 gigatons of CO2 a year, and we need to reduce our impact to net zero by around 2050. Some estimates suggest this might mean removing around ten gigatons of CO2 a year from 2050 onward. Some of these ideas for using CO2, if implemented properly, could play a role in making that more economically viable.

Some ideas for using CO2 might not get off the drawing board. But with the right investment and incentives, others may move from niche research projects into credible plans, and from the work of small businesses to the goal of entire industries. Here is a selection of the ways that one person's pollution could become another's product.

1. Make buildings

There are several ways in which buildings can be constructed with materials made from CO2. The first is obvious: use wood. Growing and sustainably harvesting trees for building means that CO2 is taken from the atmosphere, converted into a valuable commercial product, and stored as carbon in long-lived buildings.

It also reduces demand for cement, which is responsible for 10-15% of global greenhouse gas emissions through its production. New technologies, such as cross-laminated timber or acetylated wood, are making this substitution ever easier.

The second way is to use and then store CO2 in concrete-making processes, by curing cement or in the manufacture of other ingredients like aggregate.

2. Create plastic products

CO2 can be used in polymers to make durable plastics for cars and buildings. Around 60% of plastics have applications in sectors other than packaging. Plastics made from CO2 could displace plastic products made from for these sectors, particularly as they don't require toxic or dirty ingredients such as phosgenes or epoxides, and can be cheaper to make than fossil-fuel based materials. Because the CO2 molecule is a stable part of the backbone of the polymer, it can be stored in these materials for as long as they last.

Five ways to turn CO2 from pollution to a valuable product
While it will be comparatively easy for cars and trains to undergo electrification, aeroplanes will still need liquid fuels with high energy densities for a while. Credit: Milosz Maslanka/Shutterstock

3. Make fuel or fertilizers

CO2 can be used as a feedstock for many chemical processes, with hundreds of potential end products, including and urea fertilizers.

Fuels made from CO2 can exist in the form of methanol as well as more complex products like so-called synfuels. These fuels can often be blended or moved around using existing infrastructure like pipes and tankers. And although CO2 fuels are currently very costly to manufacture, in the future they might be valuable in niches like aviation or long-distance shipping, which are more difficult to decarbonize than trains and cars because they need fuels with higher energy densities.

If the CO2 product is a fuel or a fertilizer, the CO2 ends up back in the atmosphere once used. While two uses of the carbon is better than one, if the carbon atom originally came from a fossil fuel, it's not a long-term solution. To be climate neutral, the CO2 feedstock will have to be sourced from the air—so the CO2 is taken from the atmosphere, made into , and then emitted back to the atmosphere. This is currently expensive and technically challenging. Crucially, the energy required for this process also needs to be renewable.

4. Increase crop yields

There's emerging evidence that increasing the amount of carbon in soils can also increase crop yields. This is a natural form of CO2 utilization that already happens—scientists and farmers can just give it a helping hand. One particularly promising way is by using biochar—plant material that has been converted into a stable form of organic carbon via a process known as pyrolysis. Biochar buried in soils could store carbon for the long term and increase crop yields.

The general benefits of replenishing and maintaining carbon in the soil are well established, but using soil as a store of carbon is challenging because it is easily disturbed.

5. Extract more oil

Counter-intuitively, it's possible to both produce oil and store CO2. That's because injecting CO2 into an oil well increases the amount of oil that can be recovered—so-called "CO2 enhanced oil recovery".

It is actually possible to operate the well so that more CO2 is put into it than is emitted in the process of producing the oil and burning it. But policy changes would be needed to incentivize this—oil companies would not do it otherwise. And it's a temporary fix. In a world that has fully decarbonized, demand for fossil oil should be close to zero.

Nonetheless, this could be a short-term way to stimulate much needed demand for CO2 capture, as emitters could sell their waste CO2 to oil producers.

All these options for using CO2 have potential, but making them a reality will need a clear understanding of the possible unintended consequences. Many could be failures, so it'd be unwise to rely solely on any one of them, but instead, spread bets widely.


Explore further

Carbon dioxide capture and use could become big business

Provided by The Conversation

This article is republished from The Conversation under a Creative Commons license. Read the original article.The Conversation

Citation: Five ways to turn carbon dioxide from pollution to a valuable product (2020, January 21) retrieved 19 February 2020 from https://phys.org/news/2020-01-ways-carbon-dioxide-pollution-valuable.html
This document is subject to copyright. Apart from any fair dealing for the purpose of private study or research, no part may be reproduced without the written permission. The content is provided for information purposes only.
14 shares

Feedback to editors

User comments