Electron switch between molecules points way to new high-powered organic batteries

September 15, 2010
This is an illustration of an assembled set of different molecules. These molecules meet, exchange electrons and then disassemble because chloride ions, which are represented as green spheres, are present. If these chloride ions are removed, the entire process can be reversed. Credit: Credit: Jung Su Park.

The development of new organic batteries -- lightweight energy storage devices that work without the need for toxic heavy metals -- has a brighter future now that chemists have discovered a new way to pass electrons back and forth between two molecules.

The research is also a necessary step toward creating , where fuel could be generated directly from the sun, much as plants do.

University of Texas at Austin chemists Christopher Bielawski and Jonathan Sessler led the research, which was published in Science.

When molecules meet, they often form new compounds by exchanging . In some cases, the electron transfer process creates one molecule with a positive charge and one molecule with a negative charge. Molecules with opposite charges are attracted to each other and can combine to form something new.

In their research, the chemists created two molecules that could meet and exchange electrons but not unite to form a new compound.

"These molecules were effectively spring-loaded to push apart after interacting with each other," says Bielawski, professor of chemistry. "After electron transfer occurs, two positively charged molecules are formed which are repelled by each other, much like magnets held in a certain way will repel each other. We also installed a chemical switch that allowed the electron transfer process to proceed in the opposite direction."

Sessler adds, "This is the first time that the forward and backward switching of electron flow has been accomplished via a switching process at the molecular scale." Sessler is the Roland K. Pettit Centennial Chair in Chemistry at The University of Texas at Austin and a visiting professor at Yonsei University.

Bielawski says this system gives important clues for making an efficient organic battery. He says understanding the electron transfer processes in these molecules provides a way to design organic materials for storing that could then be retrieved for later use.

"I would love it if my iPhone was thinner and lighter, and the battery lasted a month or even a week instead of a day," says Bielawski. "With an organic battery, it may be possible. We are now starting to get a handle on the fundamental chemistry needed to make this dream a commercial reality."

The next step, he says, is to demonstrate these processes can occur in a condensed phase, like in a film, rather than in solution.

Organic batteries are made of organic materials instead of . They could be lightweight, could be molded into any shape, have the potential to store more energy than conventional batteries and could be safer and cheaper to produce.

The molecular switch could also be a step toward developing a technology that mimics plants' ability to harvest light and convert it to energy. With such a technology, fuel could be produced directly from the sun, rather than through a plant mediator, such as corn.

"I am excited about the prospect of coupling this kind of electron transfer 'molecular switch' with light harvesting to go after what might be an improved artificial photosynthetic device," says Sessler. "Realizing this dream would represent a big step forward for science."

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not rated yet Sep 15, 2010
Very intersting stuff. Not likely to be very applicable to batteries due to huge molecular weight, but might find some unexpected applications. One obvious is analytical chemistry for detection of ion concentrations.
Here is more details:
not rated yet Sep 15, 2010
Organic battery announced by NEC about a month ago:


The NEC version sounds like it would be great for something like a police tazer, but not good for a cell phone.
not rated yet Sep 15, 2010
Organic battery announced by NEC about a month ago:


The NEC version sounds like it would be great for something like a police tazer, but not good for a cell phone.

Might also make good buffer battery for EVs or hybrids for harvesting braking energy. That needs the big power density and ability to recharge very fast. Previously they have used supercapacitors for that. Flat discharge voltage is added plus side.
Seems that here is update:
not rated yet Sep 15, 2010
Organic battery announced by NEC about a month ago:


The NEC version sounds like it would be great for something like a police tazer, but not good for a cell phone.

Article is confusing because it assumes that battery is not using Li. Actually it is still a Li-ion battery on anode side, but that cathode is redox polymer.
Here is a detailed paper on the subject:

It sounds like a decent candidate for supercapacitors,
specially if anode would use Li-titanate instead of graphite so both sides would be high-rate capable.
As for competing with Li-ion batteries, cathode capacity and energy are still too low.
not rated yet Sep 16, 2010
I see your point about the regenerative braking PPihkala, but that's probably not a good application for the NEC technology due to limited number of charge/discharge cycles inherent in organic batteries with a Lithium electrolyte. The efficiency trends down to near zero too quickly for that use. What they have is only going to be useful for things that need to be small and light-weight and have a limited number of charge/discharge cycles over the product lifetime. That's why I was suggesting something like a tazer gun, which you hopefully won't use too many times. :)
not rated yet Sep 18, 2010
"Realizing this dream would represent a big step forward for science."

That is the understatement of the millenium

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