Evidence of a new phase in liquid hydrogen

Protium, the most common isotope of hydrogen. Image: Wikipedia.

(PhysOrg.com) -- We like to think that we’ve got hydrogen, one of the most basic of elements, figured out. However, hydrogen can still surprise, especially once scientists start probing its properties on the most fundamental levels. "We ran simulations in order to provide a quantitative map of the molecular to atomic transition in liquid hydrogen," Isaac Tamblyn tells PhysOrg.com. "Some of what we found was surprising, and could change the basic equations of state used in models involving hydrogen."

Tamblyn is a scientist at Dalhousie University in Halifax, Canada. He worked with Stanimir A. Bonev to simulate the transition in liquid , offering evidence for an unreported liquid phase, and noting some interesting structural characteristics of liquid hydrogen. Information on the simulation efforts, as well as results and conclusions, are presented in : “Structure and Phase Boundaries of Compressed Liquid Hydrogen.”

“We used first principles to model the liquid,” Tamblyn explains. “Forces between atoms were obtained using the Schrödinger equation. Velocities of the were then updated, and the system was evolved through time.”

“We ran simulations to determine what would happen under different thermodynamic conditions, like density and temperature, and monitored the stability of molecules as the simulations progressed,” Tamblyn continues. “Our transition line is based on molecular stability. The chances of a molecule surviving are greater in a molecular liquid than in an atomic one, so this is a natural way to describe the transition.”

After running the simulations, Tamblyn and Bonev then had to analyze them. “We discovered an ordering in the liquid that accounts for some of the interesting characteristics of hydrogen, such as the fact that under certain conditions, liquid hydrogen is more dense than the solid. We also found that highly ordered packing explains properties related to dissociation that were previously not well understood.”

The pair found that the simulations suggest criteria for the existence of a first-order phase transition in . “The existence of this has been debated,” Tamblyn explains, “and we provide some evidence for its possibility.”

One of the most significant things Tamblyn and Bonev discovered through their simulations, from an astrophysics standpoint, is that equations describing the properties of hydrogen might need to be updated. “This should change the modeling going forward,” Tamblyn insists. “What we found in the liquid suggests what the solid might look like, and that can help determine some of its thermal and electronic properties.”

There is a good chance that planetary models might be changed using the new information on hydrogen structure discovered through these simulations. “Some previous calculations may need to be revised,” Tamblyn predicts. He also says that the simulations hint at some of the potential effects of mixtures involving hydrogen. “We’re especially interested in the implication for hydrogen and helium mixtures.”

Going forward, Tamblyn believes there is room to expand upon the work. “We are looking at the metallization of hydrogen, following the transition into a liquid metal. We are also looking at simulating hydrogen mixtures, especially with helium, to see if our findings hold true.”

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More information: Isaac Tamblyn and Stanimir A. Bonev, “Structure and Phase Boundaries of Compressed Liquid Hydrogen,” Physical Review Letters (2010). Available online: link.aps.org/doi/10.1103/PhysRevLett.104.065702

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Feb 25, 2010
It could be phase transition followed by electride formation, analogous to sodium under high pressure.


Anyway, without experiments it's easy to predict existence of such stuff without any calculations and nothing special is about it. The experiment is, what matters in physics.

Mar 01, 2010
Makes me wonder if the Blacklight Power guys have it right about fractional quantum states in Hydrogen shells...

Mar 01, 2010
There exists a few interpretations about it. The hydrogen atoms adsorbed inside of cavities of Raney nickel could get compressed mutually, which decreases their energy levels. Another hypothesis is based on the assumption, near surface vacuum becomes slightly more dense due the presence of Casimir interaction - it's a low distance analogy of dark matter clouds, surrounding massive objects. Inside of more dense vacuum the energy levels of atoms could change, as all binding forces would become weaker there.

IMO it could enable low energy nuclear reaction in similar way, like during Arata's experiments with deuterium adsorbed on palladium. Basically, it's an analogy of surface catalysis, which speed-ups many chemical reactions - just applied to nuclear scale: the strong binding energy of hydrogen to surface decreases activation energy required for cold fusion. Maybe both mechanisms are correct, maybe some others are involved here - but this research deserves attention definitely.

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