News tagged with chemical bond
Probing hydrogen under extreme conditions
(Phys.org) -- How hydrogen--the most abundant element in the cosmos--responds to extremes of pressure and temperature is one of the major challenges in modern physical science. Moreover, knowledge gleaned ...
Apr 13, 2012 |
5 / 5 (4) |
4
|
Solved: The mystery of the nanoscale crop circles
(PhysOrg.com) -- Almost three years ago a team of scientists at the U.S. Department of Energy's Lawrence Berkeley National Laboratory (Berkeley Lab) was performing an experiment in which layers of gold mere ...
Mar 02, 2012 |
3.8 / 5 (10) |
4
|
Amazon fungi found that eat polyurethane, even without oxygen
(PhysOrg.com) -- Until now polyurethane has been considered non-biodegradable, but a group of students from Yale University in the US has found fungi that will not only eat and digest it, they will do so even in the absence ...
Two-step technique makes graphene suitable for organic chemistry
The future brightened for organic chemistry when researchers at Rice University found a highly controllable way to attach organic molecules to pristine graphene, making the miracle material suitable for a ...
Nanotechnology / Nanomaterials
Nov 29, 2011 |
4.8 / 5 (8) |
4
|
Highly selective catalyst developed for ring-closing olefin metathesis
Research carried out at Boston College, in collaboration with scientists at MIT and the University of Oxford, has led to the development of an efficient and highly selective catalyst for ring-closing olefin metathesis, one ...
Nov 02, 2011 |
not rated yet |
0
|
Building crystalline materials from nanoparticles and DNA
Nature is a master builder. Using a bottom-up approach, nature takes tiny atoms and, through chemical bonding, makes crystalline materials, like diamonds, silicon and even table salt. In all of them, the properties of the ...
Nanotechnology / Nanomaterials
Oct 13, 2011 |
5 / 5 (3) |
2
|
Advanced electron microscope sheds light on metal embrittlement
Why does a solid metal that is engineered for ductility become brittle, often suddenly and with dramatic consequences, in the presence of certain liquid metal impurities?
Sep 22, 2011 |
3 / 5 (2) |
2
|
Forces within molecules can strengthen extra-long carbon-carbon bonds
(PhysOrg.com) -- The strength of a chemical bond between atoms is the fundamental basis for a molecules stability and reactivity. Tuning the strength and accessibility of the bond can dramatically change ...
Sep 16, 2011 |
5 / 5 (4) |
1
|
Novel alloy could produce hydrogen fuel from sunlight
Scientists from the University of Kentucky and the University of Louisville have determined that an inexpensive semiconductor material can be "tweaked" to generate hydrogen from water using sunlight.
Aug 30, 2011 |
4.9 / 5 (15) |
16
|
Inexpensive catalyst that makes hydrogen gas 10 times faster than natural enzyme
Looking to nature for their muse, researchers have used a common protein to guide the design of a material that can make energy-storing hydrogen gas. The synthetic material works 10 times faster than the original ...
Aug 11, 2011 |
4.6 / 5 (20) |
9
|
Chemists devise better way to prepare workhorse molecules
In chemistry, so-called aromatic molecules compose a large and versatile family of chemical compounds that are the stuff of pharmaceuticals, electronic materials and consumer products ranging from sunscreen to plastic soda ...
Jun 09, 2011 |
not rated yet |
0
|
Turning plants into power houses
(PhysOrg.com) -- "I have a slide that has a photo of a cornfield and a big photovoltaic array," says Robert Blankenship, a scientist who studies photosynthesis at Washington University in St. Louis. "When ...
May 12, 2011 |
5 / 5 (4) |
2
|
Giant virus, tiny protein crystals show X-ray laser's power and potential
Two studies published in the February 3 issue of Nature demonstrate how the unique capabilities of the world's first hard X-ray free-electron laser -- the Linac Coherent Light Source, located at the Depart ...
Feb 02, 2011 |
4.9 / 5 (13) |
3
|
Universal solvent no match for new self-healing sticky gel
Scientists can now manufacture a synthetic version of the self-healing sticky substance that mussels use to anchor themselves to rocks in pounding ocean surf and surging tidal basins. A patent is pending on ...
Jan 27, 2011 |
4.8 / 5 (10) |
3
|
'Necropanspermia' suggested as a way of seeding life on Earth
(PhysOrg.com) -- Panspermia is a mechanism for spreading organic material throughout the galaxy, but the destructive effects of cosmic rays and ultraviolet light tend to mean most organisms would be destroyed ...
Chemical bond
A chemical bond is the physical process responsible for the attractive interactions between atoms and molecules, and that which confers stability to diatomic and polyatomic chemical compounds. The explanation of the attractive forces is a complex area that is described by the laws of quantum electrodynamics. In practice, however, chemists usually rely on quantum theory or qualitative descriptions that are less rigorous but more easily explained to describe chemical bonding. In general, strong chemical bonding is associated with the sharing or transfer of electrons between the participating atoms. Molecules, crystals, and diatomic gases—indeed most of the physical environment around us—are held together by chemical bonds, which dictate the structure of matter.
Bonds vary widely in their strength which is associated both with the energy required to break them, and the forces they exert on the atoms they hold together. Generally covalent and ionic bonds are often described as "strong", whereas hydrogen bonds and van der Waals' bonds are generally considered to be "weak," although there exist overlaps in strength within these bond classes.
Since opposite charges attract via a basic electromagnetic force, the negatively-charged electrons orbiting the nucleus and the positively-charged protons in the nucleus attract each other. Also, an electron positioned between two nuclei will be attracted to both of them. Thus, the most stable configuration of nuclei and electrons is one in which the electrons spend more time between nuclei, than anywhere else in space. These electrons cause the nuclei to be attracted to each other. However, this assembly cannot collapse to a size dictated by the volumes of these individual particles. Due to the matter wave nature of electrons and their relatively smaller mass, they occupy a very much larger amount of volume compared with the nuclei, and this volume occupied by the electrons keeps the atomic nuclei relatively far apart, as compared with the size of the nuclei themselves.
In the simplest view of a so-called covalent bond, one or more electrons (often a pair of electrons) are drawn into the space between the two atomic nuclei. Here the negatively charged electrons are attracted to the positive charges of both nuclei, instead of just their own. This overcomes the repulsion between the two positively charged nuclei of the two atoms, and so this overwhelming attraction holds the two nuclei in a relatively fixed configuration of equilibrium, even though they will still vibrate at equilibrium position. In summary, covalent bonding involves sharing of electrons in which the positively charged nuclei of two or more atoms simultaneously attract the negatively charged electrons that are being shared. In a polar covalent bond, one or more electrons are unequally shared between two nuclei.
In a simplified view of an ionic bond, the bonding electron is not shared at all, but transferred. In this type of bond, the outer atomic orbital of one atom has a vacancy which allows addition of one or more electrons. These newly added electrons potentially occupy a lower energy-state (effectively closer to more nuclear charge) than they experience in a different atom. Thus, one nucleus offers a more tightly-bound position to an electron than does another nucleus, with the result that one atom may transfer an electron to the other. This transfer causes one atom to assume a net positive charge, and the other to assume a net negative charge. The bond then results from electrostatic attraction between atoms, and the atoms become positive or negatively charged ions.
All bonds can be explained by quantum theory, but, in practice, simplification rules allow chemists to predict the strength, directionality, and polarity of bonds. The octet rule and VSEPR theory are two examples. More sophisticated theories are valence bond theory which includes orbital hybridization and resonance, and the linear combination of atomic orbitals molecular orbital method which includes ligand field theory. Electrostatics are used to describe bond polarities and the effects they have on chemical substances.
For more information about Chemical bond, read the full article at
Wikipedia.
This text uses material from Wikipedia and is available under the GNU Free Documentation License.