'Voltage Patterning' could be next step in nanostructure lithography

Mar 02, 2009 By Miranda Marquit feature

(PhysOrg.com) -- "What you want these days is to have precise control of nanostructures. Using masks and optical techniques, it is possible to control how nanostructures grow for use in practical applications," David Field tells PhysOrg.com. "This is already done in silicon devices. However, with softer materials it is a bit more difficult. Our work could make it possible for a new method of patterning that would work with a number of materials."

Field, a scientist at the University of Aarhus in Aarhus, Denmark, calls the new possibility ‘voltage patterning’. Along with his peers at Aarhus, Balog, Cicman and Jones, Field believes that the results of a recent experiment showing spontaneous dipole alignment in N2O in multilayers on a substrate of gold, could lead to a number of nanotechnology applications (they even have a patent application in for the principle behind voltage patterning). Their work appears in Physical Review Letters: “Spontaneous Dipole Alignment in Films of N2O.”

“What we’ve done,” Field explains, “is fire electrons at solids to see what happens. We’re using very low energies - which no one else has done with layers of N2O.” What they found when they sent electrons, generated using the Aarhus synchrotron, ASTRID, careening into films of N2O over gold, surprised them. “We got a current even when the voltages told us we shouldn’t. This showed that the N2O spontaneously acquired a positive charge. We think this must be due to dipole alignment.”

“Most scientists are using one thousand times the currents we were using, and that is why this wasn’t seen before,” Field says. “Such large currents would destroy the effect which we have seen in seconds or less. The very low currents we use - femtoamps - interfere negligibly with the dipole alignment.”

Varying different aspects of the set-up, like thickness and deposition temperature, created very distinct effects in the way the system behaves. “We discovered that you have to have a certain thickness for the charge to appear,” Field explains. “Once we reached a certain thickness, the voltage began increasing with the film thickness. We also found that when we increased the temperature, the voltage appeared for thinner films. However at lower temperature, once you had a thick enough film, then the voltage started to rise faster than at higher temperatures. You could get up to five volts!”

“Though this behavior is a bit complicated, the system is really well-behaved and reproducible to the millivolt level,” Field adds. “We are sure that we are seeing a real effect and not an artefact.”

Even though the Aarhus team hasn’t gone beyond this initial discovery stage, the potential applications are causing some excitement. “With current lithography techniques,” Field explains, “you have to create the patterns you want for nanostructures bit by bit. The potential for voltage patterning is that you could put down a pattern of N2O with a mask, remove the mask and then other molecules you introduce would be attracted to the where the N2O lies and be patterned accordingly. It could be very efficient.” He is quick to reiterate that this process hasn’t been tested yet, but it does have future potential to create patterns for a wide range of molecules, especially biomolecules.

Applications that could grow from this discovery include biosensor applications, lab on a chip applications and nanoxerography. “We need to get together with those in the industry who are ready to more fully develop techniques to implement the principle we have demonstrated.”

More information: Balog, Cicman, Jones and Field, “Spontaneous Dipole Alignment in Films of N2O.” Physical Review Letters (2009). Available online: link.aps.org/doi/10.1103/PhysRevLett.102.073003 .

Copyright 2009 PhysOrg.com.
All rights reserved. This material may not be published, broadcast, rewritten or redistributed in whole or part without the express written permission of PhysOrg.com.

Explore further: Researchers build reversible tractor beam that moves objects 100 times farther than other efforts

add to favorites email to friend print save as pdf

Related Stories

Twitpic to shutter service after all

1 hour ago

Twitpic on Friday put out word that the service is shutting down after all, apologizing for a "false alarm" that a merger would be its salvation.

Microsoft CEO launches diversity training effort

1 hour ago

(AP)—Microsoft CEO Satya Nadella has again apologized to employees and announced in a company-wide memo that all workers will receive expanded training on how to foster an inclusive culture as he works to repair damage ...

'Red effect' sparks interest in female monkeys

3 hours ago

Recent studies showed that the color red tends increase our attraction toward others, feelings of jealousy, and even reaction times. Now, new research shows that female monkeys also respond to the color red, ...

Recommended for you

Backpack physics: Smaller hikers carry heavier loads

20 hours ago

Hikers are generally advised that the weight of the packs they carry should correspond to their own size, with smaller individuals carrying lighter loads. Although petite backpackers might appreciate the ...

Extremely high-resolution magnetic resonance imaging

20 hours ago

For the first time, researchers have succeeded to detect a single hydrogen atom using magnetic resonance imaging, which signifies a huge increase in the technology's spatial resolution. In the future, single-atom ...

User comments : 4

Adjust slider to filter visible comments by rank

Display comments: newest first

guiding_light
5 / 5 (1) Mar 03, 2009
It's a neat effect, but with the low currents and temperatures required, it looks like one has to be very patient with this technique. This is essentially charging of N2O by low energy electrons.
BrianH
1 / 5 (1) Mar 04, 2009
?? What low temperatures? It might be 300K for all you know.
guiding_light
not rated yet Mar 05, 2009
The paper gives doubledigit Kelvin results.
ZeroDelta
not rated yet Mar 05, 2009
At least I finnaly have heard something to use with regards to large scale graphene production (ish). There is work to do when I transfer to a real college!!!