A novel avenue for engineering 2D MXene family via precious metals atomic layer deposition techniques

In this study, published in Advanced Science, the team successfully developed unique and unexplored two-dimensional (2D) nanomaterials V-MXene for the very first time coupled with precious ruthenium (Ru) through the ALD process. This breakthrough holds immense promise for various applications, both contact and non-contact mode of real-time temperature sensing at the human-machine interface.

The integration of Ru-engineered V-MXene through ALD has demonstrated a remarkable 300% enhancement in device sensing performance and durability, surpassing the capabilities of pristine V-MXene. This advancement not only paves the way towards the creation multifunctional, cutting-edge personal health care devices, but also holds great promises for the progression of clean energy conversion and storage technologies.

Moreover, the utilization of the industrially scalable ALD technique used in this research enables precise engineering of MXene surfaces with precious metals, thereby opening up new possibilities for future applications.

"We are thrilled by the potential of this breakthrough," said Professor Kim. "The precision-enabled integration of precious metals opens up a whole new world of possibilities in the development of versatile, next-generation, and safe personal health care devices, as well as clean energy conversion and , with the potential to substantially impact people's lives."

Figure 1. A schematic of atomic layer deposition process and step coverage of ALD-Ru film. Credit: Advanced Science (2023). DOI: 10.1002/advs.202206355

Figure 2. As-synthesized bulk quantity delaminated V2CTX MXene (DM-V2CTX) to develop Ru-ALD Engineered DM-V2CTX (Ru@DM-V2CTX) for real-time skin temperature sensing, noncontact touch, proximity sensing, and breathing monitoring. Credit: Advanced Science (2023). DOI: 10.1002/advs.202206355

Figure 3. Ru-ALD engineered DM-V2CTX MXene microstructure and elemental mapping. (A) HAADF STEM showing the presence of layered DM-V2CTX MXene structure and the distribution of Ru atoms/clusters, (B, C) HR-STEM of the well-defined layered structure of DM-V2CTX MXene throughout the sample and inset (B) confirms the opening of V2CTX MXene layers after the removal of Al-layers, (D) HR-STEM of both layered DM-V2CTX MXene and Ru lattices, (E) Super-X EDS elemental spectra confirming the elements V, C, Ru, and (F–I) their corresponding elemental mapping images. The atoms in Fig. 2B inset are shown with the same colors as illustrated in Figure 1 after the etching and delamination process. Credit: Advanced Science (2023). DOI: 10.1002/advs.202206355