Ocean waves propel PFAS back to land, new study finds

"The common belief is that per- and polyfluoroalkyl substances, PFAS, drain from the land into the oceans where they stay to be diluted into the deep oceans over the timescale of decades," said Ian Cousins, Professor at the Department of Environmental Science and co-author of the study. "But we've now demonstrated in multiple studies that there's a boomerang effect, and some of the toxic PFAS are re-emitted to air, transported long distances and then deposited back onto land."

Field experiments across the Atlantic Ocean conducted by co-authors Bo Sha, Post-doc at the Department of Environmental Science and Jana Johansson, former Researcher at the Department of Environmental Science, currently at Linköping University, showed PFAS concentrations in air particles surpassing seawater concentrations by over 100,000 times. Subsequent global modeling estimated the re-emission, atmospheric transport, and deposition of PFAS to land.

"Jana (Johansson) and I worked intensively for two months on a ship conducting multiple with our custom-built sea spray simulator," explained Bo Sha, the main author of the study. "While our results are scientifically impactful, they are disconcerting, creating a lot of interest among scientists, regulators, and the public."

PFAS impacting health in coastal regions

PFAS, characterized by their extreme persistence leading to their colloquial designation as "forever chemicals, "are associated with a variety of serious health conditions, including cancer, fertility issues, and compromised immune system function.

Royal Research Ship (RSS) Discovery stopped at Azores, Portugal, for supplies during the 29th Atlantic Meridional Transect (AMT29). The cruise departed from Southampton in the UK on October 13, 2019 and arrived at Punta Arenas in Chile on November 26, 2019, covering a meridional transect from approximately 50°N to 50°S. Credit: Bo Sha, Department of Environmental Science, Stockholm University

Jana Johansson operating the sea spray simulator onboard the RSS Discovery. Seawater was pumped onboard from the surrounding sea and through the sea spray simulator where sea spray aerosol was generated and sampled. Credit: Bo Sha, Department of Environmental Science, Stockholm University

Bo Sha and Jana Johansson taking ocean water samples. At each of the 28 sampling stations, samples were taken from seven varying depths ranging from the surface down to 5 km. Credit: Bo Sha, Department of Environmental Science, Stockholm University