Durable plastic pollution easily, cleanly degrades with new catalyst

The main issue behind Nylon-6, the plastic inside these nets, carpet and clothing, is that it's too strong and durable to break down on its own. So, once it's in the environment, it lingers for thousands of years, littering waterways, breaking corals and strangling birds and sea life.

Now, Northwestern University chemists have developed a new catalyst that quickly, cleanly and completely breaks down Nylon-6 in a matter of minutes—without generating harmful byproducts. Even better: The process does not require toxic solvents, expensive materials or extreme conditions, making it practical for everyday applications.

Not only could this new catalyst play an important role in , it also could perform the first step in upcycling Nylon-6 wastes into higher-value products.

The research was published on Thursday (Nov. 30) in the journal Chem.

"The whole world is aware of the plastic problem," said Northwestern's Tobin Marks, the study's senior author. "Plastic is a part of our society; we use so much of it. But the problem is: What do we do when we're finished with it? Ideally, we wouldn't burn it or put it into landfills. We would recycle it. We're developing catalysts that deconstruct these polymers, returning them to their original form, so they can be reused."

A sea turtle entangled in an abandoned fishing net. Credit: NOAA

New catalyst degrades Nylon-6 sample within minutes. Credit: Northwestern University

New process recovers 99% of monomers (shown here), nylon's building blocks. After recovering monomers, industry can upcycle nylon into higher-value products. Credit: Northwestern University