Researchers develop method for upcycling plastic waste into soap
A team led by Virginia Tech researchers has developed a new method for upcycling plastics into high-value chemicals known as surfactants, which are used to create soap, detergent, and more. The work was published in Science.
Plastics and soaps tend to have little in common when it comes to texture, appearance, and, most importantly, how they are used. But there is a surprising connection between the two on a molecular level: The chemical structure of polyethylene—one of the most commonly used plastics in the world today—is strikingly similar to that of a fatty acid, which is used as a chemical precursor to soap. Both materials are made of long carbon chains, but fatty acids have an extra group of atoms at the end of the chain.
Guoliang "Greg" Liu, associate professor of chemistry in the Virginia Tech College of Science, had long felt this similarity implied that it should be possible to convert polyethylene into fatty acids—and with a few additional steps to the process—to produce soap. The challenge was how to break a long polyethylene chain into many short—but not too short—chains and how to do it efficiently. Liu believed there was the potential for a new upcycling method that could take low-value plastic waste and turn it into a high-value, useful commodity.
Guoliang “Greg” Liu holds a common water jug in his lab at Hahn Hall South. Credit: Steven Mackay for Virginia Tech.
(From left) Eric Munyaneza and Guoliang “Greg” Liu prepare plastic materials to upcycled into a fatty acid liquid in Liu’s lab at Hahn Hall South. Munyaneza is also an author on the Science journal study. Credit: Steven Mackay for Virginia Tech.
A flask filled with waxes generated from waste polyethylene and polypropylene is heated in an oil bath, and the waxes are oxidized by a stream of airflow to produce fatty acids via catalytic oxidation. Credit: Steven Mackay for Virginia Tech.