Perovskite: New LED technology surpasses the lifetime milestone
Perovskite LEDs are an emerging technology for next-generation display, lighting and communications. While perovskite LEDs can be produced simply and at low cost, they show clear technological advantages. They are lightweight ...
However, similar to perovskite solar cells, the poor device stability of perovskite LEDs stands as the grandest challenge toward commercial applications. Typical lifespans of perovskite LEDs are on the order of 10 to 100 hours. In contrast, the minimum lifetime required for an OLED display is 10,000 hours. Researchers face great difficulty reaching this threshold, as halide perovskite semiconductors might be intrinsically unstable due to the ionic nature of their crystal structures—the ions can move around when voltages are applied to the LEDs, leading to material degradation.
Recently, a research group led by Prof. Di Dawei and Prof. Zhao Baodan at the College of Optical Science and Engineering of Zhejiang University made an important breakthrough in this area. They discovered that by using a dipolar molecular stabilizer, it is possible to make efficient and stable perovskite LEDs with ultralong lifetimes, satisfying the demands of commercial applications. The research was carried out in collaboration with the research groups of Prof. Li Cheng at Xiamen University, Prof. Hong Zijian at Zhejiang University, and Prof. Li Weiwei at NUAA and formerly at Cambridge University. A paper titled "Ultrastable near-infrared perovskite light-emitting diodes" was published by the researchers on 8 August 2022 in Nature Photonics.
Figure 1: Structure of the perovskite LED (upper left panel); structure of the dipolar molecular stabilizer, SFB10 (lower left panel); device T50 lifetimes versus the optical power output (radiance) of the perovskite LEDs (right panel). Credit: Nature Photonics (2022). DOI: 10.1038/s41566-022-01046-3
Figure 2: Long-term operation and accelerated aging experiments of the perovskite LEDs (left panel); external quantum efficiency data of the stabilized and untreated devices (right panel). Credit: Nature Photonics (2022). DOI: 10.1038/s41566-022-01046-3
Figure 4: Microscopic luminescence imaging experiments showing the effects of ion migration in perovskite samples under electric fields. Credit: Nature Photonics (2022). DOI: 10.1038/s41566-022-01046-3