Paper or plastic? Rigid waterproof coating for paper aims to reduce our dependence on plastic

It's hard to escape the fact that are, by and large, detrimental to the environment. You've probably seen images of pollution washing up on beaches, spoiling rivers and killing countless animals. Yet the problem often seems completely out of our hands given the ubiquity of plastic materials in everyday life. Professor Zenji Hiroi from the Institute for Solid State Physics at the University of Tokyo and his team explore ways materials science can help, and their recent discovery aims to replace some uses of plastic with something more sustainable: Paper.

"The main problem with plastic materials as I see it is their inability to degrade quickly and safely," said Hiroi. "There are materials that can degrade safely, such as paper, but obviously paper cannot fulfill the vast range of uses plastic can. However, we've found a way to give paper some of the nice properties of plastic, but with none of the detriments. We call it Choetsu, a low-cost biodegradable that adds waterproofing and strength to simple paper."

Choetsu is a combination of materials which, when applied to paper, spontaneously generate a strong and waterproof film when it makes contact with moisture in the air. The coating consists of safe and low-cost chemicals, mostly methyltrimethoxysilane, some isopropyl alcohol, and a small amount of tetraisopropyl titanate. Paper structures, for example food containers, are sprayed with or dipped into this liquid mixture and are dried at room temperature. Once dry, a thin layer of silica containing methyl, a type of alcohol, forms on the cellulose making up the , providing the strong and waterproof properties.

A classic origami crane made from paper and coated with Choetsu (left) and uncoated (right). When submerged in water, the coated paper crane keeps its shape while the uncoated one quickly saturates with water and starts to disintegrate. Credit: ©2022 Hiroi et al.

A section of Choetsu-coated paper a fraction of a millimeter across viewed with different kinds of X-rays to see the distribution of compounds. Si is silicon, C is carbon and Ti is titanium. Credit: ©2022 Hiroi et al.

A rendering showing the silica layer applied to a substance, not limited to paper, and titanium nanoparticles spread throughout. These can provide an antimicrobial effect as illustrated by the bacteria being destroyed in the center. Credit: ©2022 Hiroi et al.