Understanding enzyme evolution paves the way for green chemistry

Researchers at the University of Bristol have shown how laboratory evolution can give rise to highly efficient enzymes for new-to-nature reactions, opening the door for novel and more environmentally friendly ways to make ...

Machine learning discovers new sequences to boost drug delivery

Duchenne muscular dystrophy (DMD), a rare genetic disease usually diagnosed in young boys, gradually weakens muscles across the body until the heart or lungs fail. Symptoms often show up by age 5; as the disease progresses, ...

Study reveals how smell receptors work

All senses must reckon with the richness of the world, but nothing matches the challenge faced by the olfactory system that underlies our sense of smell. We need only three receptors in our eyes to sense all the colors of ...

Atmospheric acidity impacts oceanic ecology

Increased acidity in the atmosphere is disrupting the ecological balance of the oceans, according to new research led by the University of East Anglia (UEA).

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An acid (from the Latin acidus/acēre meaning sour) is a substance which reacts with a base. Commonly, acids can be identified as tasting sour, reacting with metals such as calcium, and bases like sodium carbonate. Aqueous acids have a pH of less than 7, where an acid of lower pH is typically stronger, and turn blue litmus paper red. Chemicals or substances having the property of an acid are said to be acidic.

Common examples of acids include acetic acid (in vinegar), sulfuric acid (used in car batteries), and tartaric acid (used in baking). As these three examples show, acids can be solutions, liquids, or solids. Gases such as hydrogen chloride can be acids as well. Strong acids and some concentrated weak acids are corrosive, but there are exceptions such as carboranes and boric acid.

There are three common definitions for acids: the Arrhenius definition, the Brønsted-Lowry definition, and the Lewis definition. The Arrhenius definition states that acids are substances which increase the concentration of hydronium ions (H3O+) in solution. The Brønsted-Lowry definition is an expansion: an acid is a substance which can act as a proton donor. Most acids encountered in everyday life are aqueous solutions, or can be dissolved in water, and these two definitions are most relevant. The reason why pHs of acids are less than 7 is that the concentration of hydronium ions is greater than 10−7 moles per liter. Since pH is defined as the negative logarithm of the concentration of hydronium ions, acids thus have pHs of less than 7. By the Brønsted-Lowry definition, any compound which can easily be deprotonated can be considered an acid. Examples include alcohols and amines which contain O-H or N-H fragments.

In chemistry, the Lewis definition of acidity is frequently encountered. Lewis acids are electron-pair acceptors. Examples of Lewis acids include all metal cations, and electron-deficient molecules such as boron trifluoride and aluminium trichloride. Hydronium ions are acids according to all three definitions. Interestingly, although alcohols and amines can be Brønsted-Lowry acids as mentioned above, they can also function as Lewis bases due to the lone pairs of electrons on their oxygen and nitrogen atoms.

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