Understanding the effect of catalyst spin state on reaction

From a spin state perspective, metal complex catalysts are classified into two types: closed-shell catalysts (lacking unpaired electrons, typically based on noble metals like palladium) and open-shell catalysts (with unpaired ...

Methane activation by [LnO]+: The 4f orbital matters

As the "holy grail" in the field of chemistry, the catalytic activation of methane has been a topic of great interest in the field of heterogeneous catalysis. Gas-phase experiments provide an ideal platform for exploring ...

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