This article has been reviewed according to Science X's editorial process and policies. Editors have highlighted the following attributes while ensuring the content's credibility:

fact-checked

peer-reviewed publication

trusted source

proofread

New study shows 'self-cleaning' of marine atmosphere

atmosphere
Credit: Pixabay/CC0 Public Domain

Scientists have shed new light on the "self-cleaning" capacity of the atmosphere.

This process of self-cleaning is essential to remove gaseous pollutants and regulate such as methane from the atmosphere.

Researchers were already aware that the atmosphere had this "self-cleaning" ability, but in a new study from the University York, experts have now shown a new process that increases the ability of the marine atmosphere to self-cleanse.

Using a combination of aircraft and ground-based observations, scientists were able to confirm the widespread presence of nitrous acid (HONO) in the remote Atlantic troposphere formed by so-called "renoxification", whereby photolysis of aerosol nitrate returns (NOx) and HONO to the marine atmosphere.

Historically, aerosol nitrate had been considered a permanent sink for NOx. This new process could increase the ability of the atmosphere to self-cleanse on a global scale.

Scientists say the findings, published in Science Advances, could be highly significant for and largely reconcile widespread uncertainty on the importance of renoxification.

With support from the Natural Environmental Research Council (NERC), scientists from the Wolfson Atmospheric Chemistry Laboratories (WACL) led extensive aircraft and ground-based observations in and around Cape Verde in August 2019 and February 2020.

Lead author, Professor Lucy Carpenter said, "Importantly, the observations showed that the efficiency of renoxification increased with and decreased with the concentration of nitrate."

"This observation reconciled the very large discrepancies in the rates of renoxification found across multiple laboratory and field studies."

"It was also consistent with renoxification occurring on the surface of aerosols, rather than within their bulk, a new and exciting finding with implications for how this fundamental process is controlled and parameterized in models."

Recycling of nitrogen oxides on nitrate aerosol could have important, increasing, and as yet unexplored implications for the trends and distributions of atmospheric oxidants such as , an important greenhouse gas.

More information: Simone Andersen et al, Extensive field evidence for the release of HONO from the photolysis of nitrate aerosols, Science Advances (2023). DOI: 10.1126/sciadv.add6266. www.science.org/doi/10.1126/sciadv.add6266

Journal information: Science Advances

Provided by University of York

Citation: New study shows 'self-cleaning' of marine atmosphere (2023, January 18) retrieved 21 February 2024 from https://phys.org/news/2023-01-self-cleaning-marine-atmosphere.html
This document is subject to copyright. Apart from any fair dealing for the purpose of private study or research, no part may be reproduced without the written permission. The content is provided for information purposes only.

Explore further

Sunlight-absorbing organic compounds are produced on the wet surfaces of atmospheric particles

70 shares

Feedback to editors