Researchers learn to engineer growth of crystalline materials consisting of nanometer-size gold clusters

Researchers learn to engineer growth of crystalline materials consisting of nanometer-size gold clusters
Electron microscopy image (background) of an ordered crystal consisting of 25-atom gold clusters. The data could be interpreted by a model of tightly packed polymeric chains of the clusters (light spheres). A close-up visualization of two such clusters, connected by a gold-ligand chain is shown in front. Graphics: Sami Malola, University of Jyväskylä. Credit: University of Jyvaskyla/Sami Malola

First insights into engineering crystal growth by atomically precise metal nanoclusters have been achieved in a study performed by researchers in Singapore, Saudi Arabia and Finland. The work was published in Nature Chemistry.

Ordinary solid matter consists of atoms organized in a crystal lattice. The chemical character of the atoms and lattice symmetry define the properties of the matter, for instance, whether it is a metal, a semiconductor or and electric insulator. The lattice symmetry may be changed by such as temperature or , which can induce structural transitions and transform even an electric insulator to an electric conductor, that is, a metal.

Larger identical entities such as nanoparticles or atomically precise metal nanoclusters can also organize into a , to form so called meta-materials. However, information on how to engineer the growth of such materials from their has been scarce since the is a typical self-assembling process.

Now, first insights into engineering crystal growth by atomically precise metal nanoclusters have been achieved in a study performed by researchers in Singapore, Saudi Arabia and Finland. They synthesized consisting of only 25 gold atoms, one nanometer in diameter. These clusters are soluble in water due to the ligand molecules that protect the gold. This cluster material is known to self-assemble into well-defined close packed single crystals when the water solvent is evaporated.

However, the researchers found a novel concept to regulate the crystal growth by adding tetra-alkyl-ammonium molecular ions in the solvent. These ions affect the surface chemistry of the gold clusters, and their size and concentration were observed to have an impact on the size, shape, and morphology of the formed crystals. Remarkably, high-resolution electron microscopy images of some of the crystals revealed that they consist of polymeric chains of clusters with four-gold-atom interparticle links.

The demonstrated surface chemistry opens now new ways to engineer metal cluster -based meta-materials for investigations of their electronic and optical properties.

The cluster materials were synthesized in the National University of Singapore, the electron microscopy imaging was done at the King Abdullah University of Science and Technology in Saud Arabia, and the theoretical modeling was done at the University of Jyvaskyla, Finland.

More information: Qiaofeng Yao et al, Supercrystal engineering of atomically precise gold nanoparticles promoted by surface dynamics, Nature Chemistry (2022). DOI: 10.1038/s41557-022-01079-9

Journal information: Nature Chemistry

Citation: Researchers learn to engineer growth of crystalline materials consisting of nanometer-size gold clusters (2022, November 11) retrieved 5 December 2022 from https://phys.org/news/2022-11-growth-crystalline-materials-nanometer-size-gold.html
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