Plastic upcycling: From waste to fuel for less

Plastic upcycling: From waste to fuel for less
Plastic waste may one day be upcycled to useful commodity chemicals instead of ending up in the environment. Credit: Cortland Johnson, Pacific Northwest National Laboratory

A plastics recycling innovation that does more with less, presented today at the American Chemical Society fall meeting in Chicago, simultaneously increases conversion to useful products while using less of the precious metal ruthenium.

"The key discovery we report is the very low metal load," said Pacific Northwest National Laboratory chemist Janos Szanyi, who led the research team. "This makes the much cheaper."

The new method more efficiently converts plastics to valuable commodity chemicals—a process termed "upcycling." In addition, it produces much less methane, an undesirable greenhouse gas, as a byproduct, compared with other reported methods.

"It was very interesting to us that there had been nothing previously published showing this result," said postdoctoral research scientist Linxiao Chen, who presented the research at ACS. "This research shows the opportunity to develop effective, selective and versatile catalysts for plastic upcycling."

Plastic upcycling provides a way to reuse the waste carbon now cluttering landfills and beaches. Credit: Sara Levine, Pacific Northwest National Laboratory

Less metal is more in plastic upcycling

Petroleum-based plastic waste presents an untapped source of carbon-based chemicals that can serve as the starting material for useful durable materials and fuels. Very little plastic is currently recycled, mainly for economic and practical reasons. But PNNL scientists are trying to change the dynamic by applying their expertise in efficiently breaking .

It's well known that adding hydrogen—a reaction known as hydrogenolysis—to difficult-to-recycle like polypropylene and polyethylene presents a promising strategy to convert into value-added small hydrocarbons. This process requires efficient and selective catalysts to make it economically feasible.

That's where this recent PNNL-led research excelled.

The research team discovered that reducing the amount of the precious metal ruthenium actually improved the polymer upcycling efficiency and selectivity. In a study recently published in ACS Catalysis, they showed that the improvement in efficiency happened when the low ratio of metal to support structure caused the structure to shift from an orderly array of particles to disordered rafts of atoms.

Trapped atoms

A track record of PNNL expertise in helped the team understand why less is more. The research team observed the transition to disorder on the and then used established theory to show that single atoms are actually more effective catalysts in this .

The work builds on research in atom trapping and single-atom catalysts by Yong Wang, a professor of chemical engineering at Washington State University, Pullman, and a PNNL Laboratory fellow.

"There has been a lot of effort from a material perspective to try to understand how single atoms or very small clusters can make effective catalysts," said Gutiérrez.

At ACS, Chen also described new work that explores the role of the support material in improving the efficiency of the system.

"We have investigated cheaper and more easily available support materials to replace cerium oxide," said Chen. "We found that a chemically modified titanium oxide may enable a more effective and selective pathway for polypropylene upcycling."

Learning how to tolerate chlorine

To make the method practical for use with mixed plastic recycling streams, the research team is now exploring how the presence of chlorine affects the efficiency of the chemical conversion.

"We are looking into more demanding extraction conditions," said chemist Oliver Y. Gutiérrez, an expert in for catalysis. "When you don't have a clean plastic source, in an industrial upcycling process, you have chlorine from polyvinylchloride and other sources. Chlorine can contaminate the plastic upcycling reaction. We want to understand what effect chlorine has on our system."

Now, that fundamental understanding may help convert waste that would usually end up as pollution in the environment into useful products.

More information: Disordered, Sub-Nanometer Ru Structures on CeO2 are Highly Efficient and Selective Catalysts in Polymer Upcycling by Hydrogenolysis, ACS Catalysis (2022).

Journal information: ACS Catalysis

Citation: Plastic upcycling: From waste to fuel for less (2022, August 22) retrieved 4 December 2022 from
This document is subject to copyright. Apart from any fair dealing for the purpose of private study or research, no part may be reproduced without the written permission. The content is provided for information purposes only.

Explore further

The most direct path to plastic upcycling is designing polymers specifically for reuse


Feedback to editors