New combination of materials creates record-breaking lithium-metal cell

Record-breaking lithium-metal cell
The ionic liquid electrolyte ILE (right) largely prevents structural modifications on the nickel-rich NCM88 cathode. After 1000 cycles, battery capacity still reaches 88 percent. Credit: Fanglin Wu and Dr. Matthias Künzel, KIT/HIU

Currently, lithium-ion batteries are the most prevalent solution for mobile power supply. In some applications, however, it reaches its limits. This especially holds for electric mobility, where lightweight and compact vehicles with large ranges are desired. Lithium-metal batteries may be an alternative. They are characterized by a high energy density, meaning that they store much energy per mass or volume. Still, stability is a problem, because the electrode materials react with conventional electrolyte systems.

Researchers of Karlsruhe Institute of Technology (KIT) and the Helmholtz Institute Ulm for Electrochemical Energy Storage (HIU) have now found a solution. As reported in Joule, they have used a promising new combination of materials. A cobalt-poor, nickel-rich layered cathode (NCM88) reaches a . With the usually applied, commercially available organic (LP30), however, stability leaves a lot to be desired. Storage capacity decreases with an increasing number of cycles. Professor Stefano Passerini, Director of HIU and Head of the Electrochemistry for Batteries Group, explains the reason: "In the electrolyte LP30, particles crack on the cathode. Inside these cracks, the electrolyte reacts and damages the structure. In addition, a thick mossy lithium-containing layer forms on the anode." For this reason, the scientists used a non-volatile, poorly-flammable, dual-anion ionic liquid electrolyte (ILE) instead. "With the help of ILE, structural modifications on the nickel-rich cathode can be reduced significantly," says Dr. Guk-Tae Kim from the Electrochemistry for Batteries Group of HIU.

Capacity 88 percent after 1000 cycles

The results: The lithium-metal battery with the NCM88 cathode and the ILE electrolyte reaches an energy density of 560 watt-hours per kilogram (Wh/kg)—based on the total weight of the active materials. Its initial is 214 milliampere hours per gram (mAh g-1) of the cathode material. After 1000 cycles, 88 percent of the capacity are retained. The average Coulombic efficiency, i.e., the ratio between discharge and charge capacity, is 99.94 percent. As the battery is characterized by a high safety, the researchers have made an important step towards carbon-neutral mobility.

More information: Fanglin Wu et al, Dual-anion ionic liquid electrolyte enables stable Ni-rich cathodes in lithium-metal batteries, Joule (2021). DOI: 10.1016/j.joule.2021.06.014

Journal information: Joule

Citation: New combination of materials creates record-breaking lithium-metal cell (2021, August 24) retrieved 28 March 2024 from https://phys.org/news/2021-08-combination-materials-record-breaking-lithium-metal-cell.html
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