Proliferation of electric vehicles based on high-performance, low-cost sodium-ion battery
Various automobile companies are preparing to shift from internal combustion (IC) engine vehicles to electric vehicles (EVs). However, due to higher cost, EVs are not as easily accessible to consumers; hence, several governments are subsidizing EVs to promote sales. For EV costs to compete with those of IC engine vehicles, their batteries, which account for about 30% of their cost, must be more economical than IC-based vehicles.
The Korea Institute of Science and Technology (KIST) has announced that Dr. Sang-Ok Kim's team at the Center for Energy Storage Research had developed a novel, high-performance, economical anode material for use in sodium-ion secondary batteries, which are more cost-effective than lithium-ion batteries. This novel material can store 1.5 times more electricity than the graphite anode used in commercial lithium-ion batteries and its performance does not degrade even after 200 cycles at very fast charging/discharging rates of 10 A/g.
Sodium is over 500 times more abundant in the Earth's crust than lithium; hence, sodium-ion batteries have drawn considerable attention as the next-generation secondary battery because it is 40% cheaper than lithium-ion batteries. However, compared to lithium ions, sodium ions are larger and, thus, cannot be stored as stably in graphite and silicon, which are widely used as anodes in such batteries. Hence, the development of a novel, high-capacity anode material is necessitated.
The KIST research team used molybdenum disulfide (MoS2), a metal sulfide that has garnered interest as a candidate for large-capacity anode materials. MoS2 can store a large amount of electricity, but cannot be used because of its high electrical resistance and structural instability that occur during battery operation. However, Dr. Sang-Ok Kim's team overcame this problem by creating a ceramic nano-coating layer using silicone oil, which is a low-cost, eco-friendly material. Through the simple process of mixing the MoS2 precursor with silicone oil and heat-treating the mixture, they could produce a stable heterostructure with low resistance and enhanced stability.
Furthermore, the evaluation of electrochemical properties indicated that this material could stably store at least twice as much electricity (~600 mAh/g) as the MoS2 material without coating and could maintain this capacity even after 200 rapid charge/discharge cycles. This excellent performance was achieved by the formation of the ceramic nano-coating layer with high electric storage capacity, which imparts high conductivity and rigidity to the MoS2 surface, resulting in low electrical resistance of the material and high structural stability.
Dr. Sang-Ok Kim, stated that they "could successfully solve the high resistance and structural instability problems of MoS2 through the nano-coating surface stabilization technology. As a result, we could develop a sodium-ion battery that can stably store a large amount of electricity. Our method uses cost-effective, eco-friendly materials and, if adapted for the large-scale manufacturing of anode materials, can lower production costs and, hence, boost the commercialization of sodium-ion batteries for large-capacity power storage devices."
More information: Hyojun Lim et al, Hierarchically Designed Nitrogen-Doped MoS2/Silicon Oxycarbide Nanoscale Heterostructure as High-Performance Sodium-Ion Battery Anode, ACS Nano (2021). DOI: 10.1021/acsnano.1c00797
Journal information: ACS Nano
Provided by National Research Council of Science & Technology