Researchers probe how nanoparticles affect neighbors in catalysis
Are you affected by your neighbors? So are nanoparticles in catalysts. New research from Chalmers University of Technology, Sweden, published in the journals Science Advances and Nature Communications, reveals how the nearest neighbors determine how well nanoparticles work in a catalyst.
"The long-term goal of the research is to be able to identify super-particles, to contribute to more efficient catalysts in the future. To utilize the resources better than today, we also want as many particles as possible to be actively participating in the catalytic reaction at the same time," says research leader Christoph Langhammer at the Department of Physics at Chalmers University of Technology.
Imagine a large group of neighbors gathered together to clean a communal courtyard. They set about their work, each contributing to the group effort. The only problem is that not everyone is equally active. While some work hard and efficiently, others stroll around, chatting and drinking coffee. If you only looked at the end result, it would be difficult to know who worked the most, and who simply relaxed. To determine that, you would need to monitor each person throughout the day. The same applies to the activity of metallic nanoparticles in a catalyst.
The hunt for more effective catalysts through neighborly cooperation
Inside a catalyst several particles affect how effective the reactions are. Some of the particles in the crowd are effective, while others are inactive. But the particles are often hidden within different "pores," much like in a sponge, and are therefore difficult to study.
To be able to see what is really happening inside a catalyst pore, the researchers from Chalmers University of Technology isolated a handful of copper particles in a transparent glass nanotube. When several are gathered together in the small gas-filled pipe, it becomes possible to study which particles do what, and when, in real conditions.
In the tube, the particles come into contact with an inflowing gas mixture of oxygen and carbon monoxide. When these substances react with each other on the surface of the copper particles, carbon dioxide is formed. It is the same reaction that happens when exhaust gasses are purified in a car's catalytic converter, except there, particles of platinum, palladium and rhodium are often used to break down toxic carbon monoxide instead of copper. But these metals are expensive and scarce, so researchers are looking for more resource-efficient alternatives.
"Copper can be an interesting candidate for oxidizing carbon monoxide. The challenge is that copper has a tendency to change itself during the reaction, and we need to be able to measure what oxidation state a copper particle has when it is most active inside the catalyst. With our nanoreactor, which mimics a pore inside a real catalyst, this will now be possible," says David Albinsson, Postdoctoral researcher at the Department of Physics at Chalmers and first author of two scientific articles recently published in Science Advances and Nature Communications.
Anyone who has seen an old copper rooftop or statue will recognize how the reddish-brown metal soon turns green after contact with the air and pollutants. A similar thing happens with the copper particles in the catalysts. It is therefore important to get them to work together in an effective way.
"What we have shown now is that the oxidation state of a particle can be dynamically affected by its nearest neighbors during the reaction. The hope therefore is that eventually we can save resources with the help of optimized neighborly cooperation in a catalyst," says Christoph Langhammer, professor at the Department of Physics at Chalmers.
David Albinsson et al. Operando detection of single nanoparticle activity dynamics inside a model pore catalyst material, Science Advances (2020). DOI: 10.1126/sciadv.aba7678