Prediction: Hydride compound should be superconductive at high temperature and pressure

**Theorists suggest a hydride compound should be superconductive at high temperature and pressure
Ma and colleagues predict that, under a pressure of 250 GPa, the compound Li2MgH16 will superconduct with a transition temperature of around 200C. According to their calculations, the lithium atoms (green) help prevent the hydrogen atoms (small red spheres) from forming H2, which would block superconductivity. Credit: Y. Sun et al. DOI: 10.1103/PhysRevLett.123.097001

A team of researchers at Jilin University has calculated that a certain hydride compound should be superconductive at high temperature and under very high pressure. In their paper published in the journal Physical Review Letters, the group describes the work they did that led to their theory.

For over 100 years, scientists have been intrigued by the possibility of using materials in real-world products. Such materials would solve heat problems with electronic devices and would also make them far more efficient than those available today. Unfortunately, scientists have not been able to find a material that superconducts at room temperature and ambient pressure. Most materials tested thus far become superconductive at extremely low temperatures, limiting their use in a commercial product.

In recent years, researchers have found materials that become superconductive at high temperatures. Most are hydrides, which, as their name suggests, are materials rich in hydrogen—mostly binary compounds. In this new effort, the researchers bucked the trend of finding superconducting hydrides via experimentation in the lab—instead, they have developed a theory that suggests a ternary hydride Li2MgH16 should become superconducting at a temperature of approximately 473 K and pressure of 250 GPa. The researchers note that in their theory, Li2MgH16 can actually be considered as a binary hydride (MgH16) that has been doped with lithium to serve as an electron donor. Without the lithium, the hydride would simply break down into H2 when exposed to .

Notably, the work by the team in China is purely theoretical—they have made no effort to create and test their ideas. This is because the pressure required to make the material transition to superconducting would be difficult to achieve—it is close to that found at the Earth's core. But the work does represent a change in approach to finding a material that superconducts at room temperature and —using theory and math. They suggest their work shows that conventional physics tools such as density-functional calculations can be used in the search, speeding up the process and perhaps the eventual discovery of truly usable superconducting materials.


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More information: Route to a Superconducting Phase above Room Temperature in Electron-Doped Hydride Compounds under High Pressure, Physical Review Letters (2019). journals.aps.org/prl/abstract/ … ysRevLett.123.097001
Journal information: Physical Review Letters

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Citation: Prediction: Hydride compound should be superconductive at high temperature and pressure (2019, August 27) retrieved 21 September 2019 from https://phys.org/news/2019-08-hydride-compound-superconductive-high-temperature.html
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