Breakthrough in acidic water electrolysis via ruthenium-based catalysts

Breakthrough in acidic water electrolysis via ruthenium-based catalysts
Oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) can be regarded as two trophies in the field of efficient utilization of hydrogen energy. However, in acidic OER, high applied potential was needed and the stability of the catalyst is very poor, which resulted in the slow kinetics. With Ru catalyst, the process is significantly accelerated. Credit: CUI Jie

Hydrogen fuel is clean, renewable and of high efficiency. Water electrolysis is an ideal way to produce hydrogen, yet it requires active and stable catalysts that make this process more efficient and cheaper. Without suitable catalysts, turning water into fuel only seems too good to be true.

Fortunately, a recent study is bringing this dream closer. Professor Wu Yuen's team from the University of Science and Technology of China (USTC) successfully prepared a kind of Ruthenium single atom alloy , which greatly accelerates the process of water eletrolysis with lower overpotential (220 mV).

The group successfully prepared a single atom Ruthenium (Ru) catalyst by surface defect engineering to capture and stabilize single atoms. The single atom Ru catalyst delivers a 90 mV lower overpotential to reach a of 10 mA/cm2, and an order of magnitude with a longer lifetime than that of commercial RuO2.

In this study, researchers constructed a series of alloy-supported Ru1 using different PtCu alloys through sequential acid etching and electrochemical leaching. They also found a volcano relation between (OER) activity and the lattice constant of the PtCu alloys. Density functional theory investigations reveal that the compressive strain of the Pt-skin shell engineers the electronic structure of the Ru1, allowing optimized binding of oxygen species and better resistance to over-oxidation and dissolution.

Breakthrough in acidic water electrolysis via ruthenium-based catalysts
Ru was atomically dispersed in metal support. In acidic electrolyte environment, water molecules was adsorbed on the active site Ru atom under the applied potential, and then single atom Ru catalyst boosts acidic water electrolysis producing oxygen via OOH mechanism. (Purple, blue, red and white balls represents Ru, Pt, O and H atoms, respectively.) Credit: WU Yuen

Compared with Iridium-based systems, which have better dissolution resistance, Ru-based ones have more abundant reserves and have been evaluated to be a more active OER catalyst due to its lower overpotential.

This research makes through easier and more efficient, and allows people to see the great potential of hydrogen as an alternative new energy in the future.

Nevertheless, till now, the stability problem of catalyst hasn't been completely resolved. "There are still many explorations left to further improve the reaction system and we are going to continue designing experiments and trying to find the best way to boost activity and stability of catalysts." said Ph.D. YAO.

More information: Yancai Yao et al, Engineering the electronic structure of single atom Ru sites via compressive strain boosts acidic water oxidation electrocatalysis, Nature Catalysis (2019). DOI: 10.1038/s41929-019-0246-2

Journal information: Nature Catalysis

Provided by University of Science and Technology of China

Citation: Breakthrough in acidic water electrolysis via ruthenium-based catalysts (2019, March 22) retrieved 17 April 2024 from
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