Scientists study impact of lithium dendrites on cathode materials

December 5, 2018, Environmental Molecular Sciences Laboratory
Scientists study impact of lithium dendrites on cathode materials
Researchers imaged the structural and chemical evolutions of LiCoO2 cathodes upon Li dendrite contact at an atomic scale. A spontaneous, irreversible conversion reaction leads to the formation of Co metal and Li2O, with CoO as a metastable reaction intermediate. Credit: Environmental Molecular Sciences Laboratory

Rechargeable lithium (Li) batteries are the most widely used energy storage devices found in consumer electronics and electric vehicles today. There are challenges, though, to optimizing their capacity, recyclability, and stability. During a Li battery's charge-discharge cycles, highly localized Li dendrites – strands of Li that grow inside batteries – can form and hurt the battery's performance.

"Lithium dendrites are fine strands, like whiskers, that can come in contact with and cause a chain of irreversible, spontaneous chemical reactions," said Yingge Du, a researcher from Pacific Northwest National Laboratory (PNNL) who recently led a study to visualize this phenomena. "It can lead to performance decay, short circuiting, and safety hazards," he added.

Du and his team sought to pinpoint the exact failure mechanism. To do so, they needed to precisely control how and when the Li dendrites came into contact with the materials. The team used in situ (TEM) to directly image the structural and chemical evolutions of lithium cobalt oxide (LiCoO2) thin film cathodes on Li contact. "LiCoO2 is still one of the most widely used cathode materials," said Du, "and making it into well-defined single-crystalline form by pulsed can unleash the power of advanced electron microscopy." Using this approach, researchers discovered an unexpected Li propagation pathway and detailed steps that lead to the cathode failure.

Their study, "Direct Visualization of Li Dendrite Effect on LiCoO2 Cathode by In Situ TEM," was recently published in Small and featured on its cover.

To meet the increasing demands for large-scale , there is an urgent need for researchers to develop safer, rechargeable batteries with higher energy output. Li metal has been regarded as an ideal, high-capacity anode material. However, its use is greatly hampered by the formation of Li dendrites that can penetrate the separator – a permeable membrane placed between a battery's anode and cathode. Once Li dendrites are in direct contact with cathode materials, a chain of irreversible, spontaneous chemical reactions can occur, leading to performance decay, short circuiting, and safety hazards.

While significant efforts have been devoted to detect, understand, and prevent the Li dendrite formation within the electrolytes, little is known regarding the detailed reaction pathways involving Li metal and cathode materials. Bridging this knowledge gap may provide detection and design principles that are critical to future energy storage solutions.

In this study, Du and his team of researchers at PNNL studied Li dendrites and their effect on cathode materials. They sought to understand the detailed reaction pathways, which could lead to the development of better Li batteries.

Using pulsed-laser deposition, Du and his team fabricated well-defined, epitaxial LiCoO2 thin films with controlled crystallographic orientations to serve as the model cathode materials. A Li metal tip was used to mimic the Li dendrite inside a TEM to study its reaction with prepared LiCoO2 samples.

Advanced microscopy and spectroscopy techniques – including scanning transmission electron spectroscopy, nanobeam diffraction, and electron-energy loss spectroscopy – allowed such reactions to be investigated with high spatial and temporal resolution. In combination with density functional theory calculations, researchers elucidated the reaction steps, intermediates, and final products at an unprecedented level. An unexpected Li diffusion direction perpendicular to the Li-containing planes was found, which tore the LiCoO2 crystal apart, generating large amount of grain boundaries and antiphase boundaries. While Co metal and Li2O were found to be the final products of the full conversion reaction, CoO was identified as a metastable intermediate at the reaction front as a result of facile phase transition from LiCoO2.

"The reaction steps and intermediates revealed provide a clear failure mechanism for the LiCoO2 cathodes caused by Li dendrites, and may also offer insights into the over-discharge processes in cathodes," remarked Du.

Continuing this work, Du's team intends to fabricate all-solid-state batteries by multi-step deposition processes using pulsed-laser deposition to better understand the ion transport processes across the well-defined interfaces.

Explore further: Nanotubes may give the world better batteries

More information: Zhenzhong Yang et al. Direct Visualization of Li Dendrite Effect on LiCoO2 Cathode by In Situ TEM, Small (2018). DOI: 10.1002/smll.201803108

Related Stories

Nanotubes may give the world better batteries

October 25, 2018

Rice University scientists are counting on films of carbon nanotubes to make high-powered, fast-charging lithium metal batteries a logical replacement for common lithium-ion batteries.

A novel approach of improving battery performance

September 18, 2018

New technological developments by UNIST researchers promise to significantly boost the performance of lithium metal batteries in promising research for the next-generation of rechargeable batteries. The study also validates ...

Recommended for you

Archaeologists discover Incan tomb in Peru

February 16, 2019

Peruvian archaeologists discovered an Incan tomb in the north of the country where an elite member of the pre-Columbian empire was buried, one of the investigators announced Friday.

What rising seas mean for local economies

February 15, 2019

Impacts from climate change are not always easy to see. But for many local businesses in coastal communities across the United States, the evidence is right outside their doors—or in their parking lots.

Where is the universe hiding its missing mass?

February 15, 2019

Astronomers have spent decades looking for something that sounds like it would be hard to miss: about a third of the "normal" matter in the Universe. New results from NASA's Chandra X-ray Observatory may have helped them ...

The friendly extortioner takes it all

February 15, 2019

Cooperating with other people makes many things easier. However, competition is also a characteristic aspect of our society. In their struggle for contracts and positions, people have to be more successful than their competitors ...


Please sign in to add a comment. Registration is free, and takes less than a minute. Read more

Click here to reset your password.
Sign in to get notified via email when new comments are made.