Optimization of alloy materials: Diffusion processes in nano particles decoded

November 14, 2018, Graz University of Technology
Electron microscopic image of an aluminium nano-precipitate with atom-sized diffusion channels Credit: TU Graz / FELMI

aluminum alloys have unique material properties and are indispensable materials in aircraft manufacturing and space technology. With the help of high-resolution electron tomography, researchers at TU Graz have for the first time decoded mechanisms crucial for understanding these properties. The research results have recently been published in Nature Materials.

Nano structures responsible for material quality

Alloy elements such as scandium and zircon are added to the aluminum matrix to improve the strength, corrosion resistance and weldability of aluminum alloys. After further treatment, so-called nano-precipitates, are formed. These are tiny roundish particles only a few nanometres in size. Their form, atomic and the 'struggle' of the scandium and zircon atoms for the 'best place' in the crystal lattice are decisive for the properties and usability of the material.

The researchers analysed these structures with the help of the Austrian Scanning Transmission Electron Microscope (ASTEM) at the Graz Centre for Electron Microscopy (ZFE). The device can produce high-resolution element mappings of three-dimensional structures. "The tomographic analysis provided an image which, surprisingly, could not be interpreted according to the previous level of knowledge," said Gerald Kothleitner, head of the working group for analytic transmission at the TU Graz's Institute of Electron Microscopy and Nanoanalysis. "We detected anomalies in the generated core-shell structures. On the one hand, we found higher quantities of aluminum in the nano-precipitates then we had presumed. On the other hand, we discovered a zircon-enriched core as well as border zones between the core and shell with an almost perfect composition and crystal structure."

Quantum mechanics and Monte Carlo methods provide answers

To track down this phenomenon of self-organisation, researchers from the Institute of Electron Microscopy and Nanoanalysis (FELMI) and the Institute of Materials Science, Joining and Forming (IMAT) fell back on and simulations. They found that the system separates itself and forms atomically narrow channels in which the foreign atoms can diffuse. Atoms encountering each other block these channels and stabilise the system. Doctoral student Angelina Orthacker gives a graphic explanation of the movement of the atoms: "The diffusion process can be compared with the formation of an emergency corridor in an urban area with heavy traffic. The traffic manages to organise itself in a split second to enable the free flow of emergency vehicles. But it only takes a few individual vehicles to block the emergency corridor, thus stopping it from working." And this is exactly the same behaviour in the interior of aluminum alloys. "Emergency corridors" promote the material transport of scandium and zircon atoms and even slight disturbances stop this transport reaction. The research team presumes that the new findings about these diffusion processes also play a role in other multi-component alloys. Their properties can now be adjusted even more.

Explore further: Researchers measure light fields in 3-D

More information: Angelina Orthacker et al, Diffusion-defining atomic-scale spinodal decomposition within nanoprecipitates, Nature Materials (2018). DOI: 10.1038/s41563-018-0209-z

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