Improved efficiency and stability of CQD solar cells using an organic thin film

August 27, 2018, The Korea Advanced Institute of Science and Technology (KAIST)
Improved efficiency and stability of CQD solar cells using an organic thin film
Figure 1. The schematic of the equilibrated structure of the amorphous organic film. Credit: The Korea Advanced Institute of Science and Technology (KAIST)

Recently, the power conversion efficiency (PCE) of colloidal quantum dot (CQD)-based solar cells has been enhanced, paving the way for their commercialization in various fields; nevertheless, they are still a long way from being commercialized due to their efficiency not matching their stability. In this research, a KAIST team achieved highly stable and efficient CQD-based solar cells by using an amorphous organic layer to block oxygen and water permeation.

CQD-based solar cells are lightweight, flexible, and they boost light harvesting by absorbing near-infrared light. They draw special attention for their optical properties controlled efficiently by changing the quantum dot sizes. However, they are still incompatible with existing solar cells in terms of efficiency, stability, and cost. Therefore, there is great demand for a novel technology that can simultaneously improve both PCE and stability while using an inexpensive electrode material.

Responding to this demand, Professor Jung-Yong Lee from the Graduate School of Energy, Environment, Water and Sustainability and his team introduced a technology to improve the efficiency and stability of CQD-based solar cells.

The team found that an amorphous organic thin film has a strong resistance to oxygen and water. Using these properties, they employed this doped organic layer as a top-hole selective layer (HSL) for the PbS CQD solar cells, and confirmed that the hydro/oxo-phobic properties of the layer efficiently protected the PbS layer. According to the molecular dynamics simulations, the layer significantly postponed the oxygen and water permeation into the PbS layer. Moreover, the efficient injection of the holes in the layer reduced interfacial resistance and improved performance.

Figure 2. Schematic illustration of CQD-based solar cells and graphs showing their performance. Credit: The Korea Advanced Institute of Science and Technology (KAIST)

With this technology, the team finally developed CQD-based solar cells with excellent stability. The PCE of their device stood at 11.7 percent and maintained over 90 percent of its initial performance when stored for one year under ambient conditions.

Professor Lee said, "This technology can be also applied to QD LEDs and Perovskite devices. I hope this technology can hasten the commercialization of CQD-based ."

Explore further: Bright future for solar cell technology

More information: Se-Woong Baek et al. A hydro/oxo-phobic top hole-selective layer for efficient and stable colloidal quantum dot solar cells, Energy & Environmental Science (2018). DOI: 10.1039/c7ee03184j

Related Stories

Semi-transparent perovskite solar cells for solar windows

May 22, 2017

Scientists are exploring ways to develop transparent or semi-transparent solar cells as a substitute for glass walls in modern buildings with the aim of harnessing solar energy. But this has proven challenging, because transparency ...

Recommended for you

Privacy becomes a selling point at tech show

January 7, 2019

Apple is not among the exhibitors at the 2019 Consumer Electronics Show, but that didn't prevent the iPhone maker from sending a message to attendees on a large billboard.

China's Huawei unveils chip for global big data market

January 7, 2019

Huawei Technologies Ltd. showed off a new processor chip for data centers and cloud computing Monday, expanding into new and growing markets despite Western warnings the company might be a security risk.


Please sign in to add a comment. Registration is free, and takes less than a minute. Read more

Click here to reset your password.
Sign in to get notified via email when new comments are made.