How to build efficient organic solar cells

July 17, 2018, Linköping University
Feng Gao, associate professor at Linköping University, Sweden. Credit: Göran Billeson

Organic solar cells, made from carbon-based materials, present unique advantages compared with other solar cell technologies. For example, they can be manufactured through low-cost printing technologies, and they can be made semi-transparent with selectable colours, which can be used architecturally in building integration. Their flexibility and low weight make them perfect for powering the sensors for the internet of things applications.

A key challenge facing the development of organic solar cells is that they usually have large losses. Now, 25 researchers from seven research institutes have drawn up rules for designing high-efficiency organic solar cells. The research is led by Feng Gao, associate professor at Linkoping University, Sweden.

"We have formulated some rational design rules to minimise energy losses in organic solar cells. Following these rules, we present a range of examples with low energy losses and high power conversion efficencies," says Feng Gao, associate professor at the Division of Biomolecular and Organic Electronics at Linkoping University.

The design rules, which challenge some previously held ideas, have been published in an article in the prestigious journal Nature Materials.

Using these design rules, organic solar cells promise to catch up with their competitors with respect to power conversion efficiency, which measures the fraction of the energy in the sun´s radiation that is converted to electricity. The theoretical limit for the fraction of the sun´s energy that can be obtained in solar cells is around 33 percent. Laboratory experiments with have achieved 25 percent at best. Researchers have until now believed that the limit for organic solar cells is lower.

"But we now know that there is no difference—the theoretical limit is the same for solar manufactured from silicon, perovskites or polymers," says Olle Inganas, professor of biomolecular and organic electronics, Linkoping university.

When photons from the sun are absorbed by the semiconducting polymer in a solar cell, electrons in the donor material are raised to an excited state, and holes are formed in the ground state to which the electrons remain attracted. In order to separate these bound electrons and holes, an acceptor material is added. However, this acceptor material usually results in extra energy losses, an issue that has bothered the organic solar cell community for over two decades.

The article in Nature Materials presents two fundamental rules to minimise for highly efficient :

  • Minimise the energy offset between donor and acceptor components.
  • Make sure that the low-gap component in the blend has a high photoluminescence.

The researchers at the seven research institutes in the US, China and Europe have together produced around a dozen , some of which have been reported previously and others that are completely new. They have used these to demonstrate that the new theory agrees with experimental results, even though it is somewhat incompatible with what was previously believed.

Explore further: Efficient organic solar cells with very low driving force

More information: Deping Qian et al, Design rules for minimizing voltage losses in high-efficiency organic solar cells, Nature Materials (2018). DOI: 10.1038/s41563-018-0128-z

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antialias_physorg
3 / 5 (2) Jul 17, 2018
The theoretical limit for the fraction of the sun´s energy that can be obtained in solar cells is around 33 percent.

Note that this is for single junction solar cells. Multiple junction solar cells under concentrated sunlight can go considerably higher.
Current record is about 45%...theoretical limit is about 85%.
Of course these are expensive lab types, so don't expect 30% efficient solar cells to hit the market any time soon - particularly since a normal home roof offers ample space to power a home using the current efficiencies available on the market.

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