Lining MOF pockets to detect noxious gases

May 3, 2018, King Abdullah University of Science and Technology
Lining MOF pockets to detect noxious gases
Sulfur dioxide molecules (red and yellow) are selectively taken up by pores in the metal-organic framework. Credit: Valeriya Chernikova

A porous material with tailor-made pockets stitched into its structure is a promising material for sensing noxious gases. A thin film of the material, coated onto an electrode, formed an electronic sensor that could detect traces of sulfur dioxide gas. The sensor is a significant step toward real-world devices that can sniff out dangerous gases in real air.

Although several lab-based analytical instruments can detect traces of a specific gas in the air, these instruments are typically large, expensive, power-hungry machines. There is still a need for small, inexpensive, energy-efficient that, for example, could be widely deployed around industrial sites to continually monitor air quality.

One promising way to make such sensors involves porous materials called metal-organic frameworks (MOFs). By making the MOF from different metal atoms and organic linkers, researchers can create materials that selectively absorb specific gases into tailor-made pockets within the structure. Two KAUST research groups, led by materials scientist, Mohamed Eddaoudi, and electronic engineer, Khaled Salama, recently teamed up to develop MOF-based gas sensors.

The first step was completed in 2015 when the team made a proof-of-concept sensor by coating a MOF layer on to an electrode. The device senses gases in a similar way that a touchscreen senses a finger. The gas changes the MOF sensor's capacitance, an electronic property that can be directly measured using the electrode.

Now, the team is working toward specific applications. "Our current work aims to identify the ideal MOF, in terms of sensitivity and selectivity, for detection of sulfur dioxide," says Valeriya Chernikova, a Ph.D. student from Eddaoudi's lab.

The researchers selected an indium-based version of a MOF called MFM-300 as their sensor material. A thin film of the material could be grown onto the electrode under mild conditions that do not damage the sensor circuit. The resulting material forms pockets lined with two -OH groups and four C-H groups that selectively bind sulfur-dioxide molecules. In lab tests using simple mixtures of gases, the sensor could detect at concentrations of just a few parts per billion.

To use the technology for real air—which comprises a much more complex mixture of gases—the next step is to develop sensor arrays that pool the responses of multiple MOF , Chernikova says. "The data will be processed using various statistical and machine learning algorithms to improve the accuracy of the sensor's response," she continues. "This is commonly referred to as an 'artificial nose'."

Explore further: Tunable porous MOF materials interface with electrodes to sound the alarm at the first sniff of hydrogen sulfide

More information: Valeriya Chernikova et al. Highly sensitive and selective SO2 MOF sensor: the integration of MFM-300 MOF as a sensitive layer on a capacitive interdigitated electrode, Journal of Materials Chemistry A (2018). DOI: 10.1039/c7ta10538j

Christos Sapsanis et al. Insights on Capacitive Interdigitated Electrodes Coated with MOF Thin Films: Humidity and VOCs Sensing as a Case Study, Sensors (2015). DOI: 10.3390/s150818153

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