Controlling the flow of electrons within circuits is achieved through the appropriate choice of materials. Metals allow electrons to flow freely and insulators prevent conduction. In general, the electrical properties of a material are determined when the material is fabricated and cannot be changed afterwards without changing the material. However, there are materials that can exhibit metal or insulator behaviour depending on their temperature. Being able switch their properties, these materials could lead to a new generation of electronic devices.
Vanadium dioxide (VO2) is one such material. It can switch from an insulating phase to a metallic phase just above room temperature, a feature already exploited for sensors. However, the reason that its properties change so dramatically has been a matter of scientific debate for over 50 years.
One of the challenges in understanding why and how this switch occurs is a process called phase separation. The insulator-metal phase transition is similar to the ice-liquid transition in water. When ice melts, both liquid and solid water can coexist in separate regions. Similarly, in VO2, insulating and metallic regions of the material can coexist during the transition. But unlike water, in which the two phases are often large enough to see with the naked eye, in VO2, this separation occurs on the nanoscale, and it is thus challenging to observe. As a result, it has been hard to determine if the true properties of each phase, or a mixture of both phases, are being measured.
X-rays are a key tool for understanding the properties of materials, but it is hard to build lenses for microscopes that can detect them. However, in a recent study published in Nano Letters, a team of researchers from ICFO and ALBA in Barcelona, the Technisch Universitat and Max-Born Institute in Berlin, and Vanderbilt University in Tennessee, has finally been able to probe the phase transitions that occur in thin films of VO2 using resonant soft X-ray holography. This technique is capable of imaging the electronic and structural changes in this material with an unprecedented resolution at the nanoscale without the need of a lens.
By looking at the material with 50 nm resolution, the scientists were able to observe that defects in the material play an important role in initiating the phase transition from the insulator to the metal. However, more importantly, the authors also observed a third intermediate state formed during the phase transformation. While some regions transformed directly from the insulating to the metallic phase, others transformed into a second, different insulating state before becoming metallic at higher temperatures with the exact pathway taken depending on the defects present in the material. The coexistence of three phases has radically changed the views of previous studies that assumed the presence of only two states during the transition. Even more, the study presents new ways in which the transition could be controlled.
In addition to the results obtained on the phase transition in VO2, the work also highlights the possibilities that X-ray holography offers for studying materials on the nanoscale. The technique is the only method that can image real-time nanoscale dynamics and is now being used to study the properties of other intriguing materials such as high temperature superconductors.
Explore further: Phase transition discovery opens the door to new electronics