Improved understanding of groundbreaking liquid-metal 2-D technique

May 2, 2018, ARC Centres of Excellence
Improved understanding of groundbreaking liquid-metal 2-D technique
Credit: ARC Centres of Excellence

Last year, FLEET researchers at RMIT developed a ground-breaking new method of depositing atomically-thin (two-dimensional) crystals using molten metals, described as a 'once-in-a-decade' advance.

Earlier this year, the same research team expanded the new method from controlled to , and has properly characterised the for key tin oxides, which should allow improved control of target growth.

The technique developed at RMIT last year introduced (gallium-based) as a successful reaction environment for the synthesis of desirable, atomically-thin oxides that were unattainable using prior methods. It's a process so cheap and simple that it could be done on a kitchen stove by a non-scientist.

While the initial study used costly, specially-designed alloys and an often tightly-controlled environment, this latest research has confirmed that high-quality 2-D materials can be formed in ambient conditions using cheaper liquid tin, simplifying future research and applications.

Researchers also characterised the growth mechanism for the first time, creating a 'road map' of crystal formation and growth. Such growth proved surprisingly complex, with small 'islands' of tin-oxides (SnOx) forming on larger, perfect 2-D tin monoxide (SnO) monolayers, before thickening and taking on more oxygen to become tin dioxide (SnO2).

Transmission electron microscopy (TEM) images of (a) fresh, (b) yellow, (c) pink and (d) grey tin oxides. Credit: ARC Centres of Excellence
Future applications

This simple, repeatable method of growing 2-D tin-oxide crystals can be expanded to other low-melting point liquid metals and their alloys.

Having properly characterised growth mechanisms, researchers believe it should be possible to control the rate of surface oxide formation by careful control of the atmospheric oxygen content, and hence control the number and thickness of oxide layers and resulting stoichiometry.

Tin oxides are of particular interest as 2-D materials. Electronically, they can be both p-type (SnO) or n-type (SnO2) semiconductors, which is of great interest to field effect transistor (FET) designers.

Evolution of 2-D tin oxides on the surface of molten tin was published in Chemical Communications in January 2018.

The study was conducted using the facilities and expertise of the Australian Microscopy and Microanalysis Research Facility at the RMIT Microscopy & Microanalysis Facility, and the Micro Nano Research Facility at RMIT. Co-author Torben Daeneke received support from the RMIT Vice Chancellor's research fellow scheme.

Explore further: Liquid metal discovery ushers in new wave of chemistry and electronics

More information: P. Atkin et al. Evolution of 2D tin oxides on the surface of molten tin, Chemical Communications (2018). DOI: 10.1039/C7CC09040D

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