Credit: American Chemical Society
The first step after buildings collapse from an earthquake, bombing or other disaster is to rescue people who could be trapped in the rubble. But finding entrapped humans among the ruins can be challenging. Scientists now report in the ACS journal Analytical Chemistry the development of an inexpensive, selective sensor that is light and portable enough for first responders to hold in their hands or for drones to carry on a search for survivors.
In the hours following a destruction-causing event, the survival rate of people stuck in the rubble rapidly drops, so it's critical to get in there fast. Current approaches include the use of human-sniffing dogs and acoustic probes that can detect cries for help. But these methods have drawbacks, such as the limited availability of canines and the silence of unconscious victims. Devices that detect a human chemical signature, which includes molecules that are exhaled or that waft off the skin, are promising. But so far, these devices are too bulky and expensive for wide implementation, and they can miss signals that are present at low concentrations. So, Sotiris E. Pratsinis and colleagues wanted to develop an affordable, compact sensor array to detect even the most faint signs of life.
The researchers built their palm-sized sensor array from three existing gas sensors, each tailored to detect a specific chemical emitted by breath or skin: acetone, ammonia or isoprene. They also included two commercially available sensors for detecting humidity and CO2. In a human entrapment simulation, the sensors rapidly detected tiny amounts of these chemicals, at levels unprecedented for portable detectors—down to three parts per billion. The next step is to test the sensor array in the field under conditions similar to those expected in the aftermath of a calamity.
More information: Andreas T. Güntner et al. Sniffing Entrapped Humans with Sensor Arrays, Analytical Chemistry (2018). DOI: 10.1021/acs.analchem.8b00237
Abstract
Earthquakes are lethal natural disasters frequently burying people alive under collapsed buildings. Tracking entrapped humans from their unique volatile chemical signature with hand-held devices would accelerate urban search and rescue (USaR) efforts. Here, a pilot study is presented with compact and orthogonal sensor arrays to detect the breath- and skin-emitted metabolic tracers acetone, ammonia, isoprene, CO2, and relative humidity (RH), all together serving as sign of life. It consists of three nanostructured metal-oxide sensors (Si-doped WO3, Si-doped MoO3, and Ti-doped ZnO), each specifically tailored at the nanoscale for highly sensitive and selective tracer detection along with commercial CO2 and humidity sensors. When tested on humans enclosed in plethysmography chambers to simulate entrapment, this sensor array rapidly detected sub-ppm acetone, ammonia, and isoprene concentrations with high accuracies (19, 21, and 3 ppb, respectively) and precision, unprecedented by portable sensors but required for USaR. These results were in good agreement (Pearson's correlation coefficients ≥0.9) with benchtop selective reagent ionization time-of-flight mass spectrometry (SRI-TOF-MS). As a result, an inexpensive sensor array is presented that can be integrated readily into hand-held or even drone-carried detectors for first responders to rapidly screen affected terrain.
Journal information: Analytical Chemistry
Provided by American Chemical Society
