Researchers find manganese oxide-coated filters remove contaminants from hospital wastewater

April 11, 2018 by Jennifer Matthews, Pennsylvania State University
Biogenic manganese oxide-coated coir fiber collected from the coal mine drainage treatment system in Glasgow, Pennsylvania. Credit: Penn State

Researchers at Penn State have developed a water filtration system that removes contaminants and reduces toxicity in hospital wastewater.

Contaminants, including antibiotics, pharmaceuticals and steroids, are increasingly being detected in surface waters and drinking water sources. These can have a huge impact on both human and aquatic health, so effective removal is essential to protect the health and safety of water resources. 

"There have been a number of urban sewer inventories that have identified hospitals as a major contributor of drugs and hormones and other contaminants that end up at ," said Bill Burgos, professor of environmental engineering at Penn State. 

In fact, hospitals may contribute upwards of half the total load of contaminants carried to regional wastewater treatment plants, said Burgos. Once there, elimination can be difficult because the chemicals become diluted, yet they still pose a health threat due to their high biological potency. 

"One way to destroy these compounds is through chemical oxidation," Burgos said. "Manganese oxides are very powerful oxidants and are known to be nonselective, so they are highly reactive with just about any oxidizable organic compound, including those found in hospital wastewater." 

Conceptual artwork of research project using biogenic manganese oxides produced in coal mine drainage treatment systems for point-of-entry treatment of hospital wastewater. Drawing by Audrey Stallworth, graduate student in environmental engineering. Credit: Penn State

To test the effectiveness of (MnOx), the researchers collected wastewater samples from the Penn State Health Milton S. Hershey Medical Center and obtained biogenic MnOx-coated coir fiber from a metal removal unit in Glasgow, Pennsylvania operated by EcoIslands LLC. The MnOx-coated fiber was then reacted with the hospital wastewaters to evaluate performance. 

Chemical analyses showed that biogenic MnOx-coated coir fiber filters were very effective at removing contaminants from wastewaters. Of the 36 organic micro-pollutants detected, 21 were removed by more than 94 percent after a 24-hour reaction period. 

Consistent with these results, bioanalytical assays, which test the potential toxicity of the to humans, also revealed that biologically active compounds were removed below detection levels. 

"Not only do we have chemical evidence that these filters remove these contaminants, we also have biological evidence that the potential human toxicity was dramatically reduced," Burgos said.

Metal removal units operated by EcoIslands, LLC set up as a demonstration project at the coal mine drainage treatment system in Glasgow, Pennsylvania. Coir fiber was used to fill all of the reactors to promote biological removal of dissolved manganese. Credit: Penn State

In addition, the MnOx used was formed as part of a coal mine drainage treatment system, and its reuse converts a waste product into a commodity.

The team's next steps include reducing treatment times, testing a flow-through configuration, screening different biogenic MnOx sources, and beginning field studies.

Explore further: Anaerobic microfiltration membranes for wastewater could slow the spread of antibiotic resistance

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