Tracking mechanisms of crystallization in real time

March 12, 2018, Environmental Molecular Sciences Laboratory
Tracking mechanisms of crystallization in real time
Alkaline solutions of aluminum and sodium ions form complex gels (see example) composed of aluminum metal center networks. During crystallization, these networks release ions whose structure is influenced by the presence of large concentrations of sodium ions and solute/solvent organization. Credit: Environmental Molecular Sciences Laboratory

Researchers at the Interfacial Dynamics in Radioactive Environments and Materials (IDREAM) Energy Frontier Research Center quantified transient penta-coordinated Al3+ species during the crystallization of gibbsite from hydrous aluminum gels in solutions of concentrated sodium hydroxide. The research shows that concentrated electrolytes in solution affect hydrogen bonding, ion interactions, and coordination geometries in currently unpredictable ways.

These mechanistic studies support the development of new process flow sheets to accelerate the processing of radioactive wastes at two Department of Energy sites. Further, the studies may provide less energy-intensive routes for industrial production.

Gibbsite (α-Al(OH)3) is an important mineral resource for industrial aluminum production. It is also present in large quantities in the high-level tanks at U.S. Department of Energy sites in Washington state and South Carolina. Traditional processing for either aluminum production or radioactive treatment is an energy-intensive activity. Processing involves heating to facilitate dissolution of gibbsite in highly alkaline solutions of concentrated electrolytes. Heating is followed by cooling to encourage precipitation from these chemically extreme systems.

For radioactive waste treatment, the dissolution and precipitation steps are often quite slow. Why? In part, both processes involve changes in the coordination geometry of the trivalent aluminum. In the solid phase, it is six coordinate to give an octahedral geometry. To move into the solution phase, the aluminum ion must change its geometry to a four-coordinate tetrahedral form.

Led by Jian Zhi Hu and Kevin Rosso, the team conducted high-field magic angle spinning nuclear magnetic resonance spectroscopy studies that probed ion interactions, solute organization, and solvent properties during gibbsite precipitation. The team captured real-time system dynamics as a function of experimental conditions, revealing previously unknown mechanistic details.

The team's work shows that the change in coordination is not a simple transition between the tetrahedral to octahedral species. The change involves an intermediate penta-coordinated aluminum metal center. Further, these species are influenced by subtle changes in solute and solvent organization. These changes lead to gel networks that can sometimes facilitate formation or dissolution of the solid phase. Understanding how aluminum coordination changes in extreme environments may lead to efficiencies in aluminum production and accelerate radioactive waste processing.

Explore further: Mastering tailored design of aluminum nanomaterials

More information: Jian Zhi Hu et al. Transitions in Al Coordination during Gibbsite Crystallization Using High-Field 27Al and 23Na MAS NMR Spectroscopy, The Journal of Physical Chemistry C (2017). DOI: 10.1021/acs.jpcc.7b10424

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