Volatility surprises arise in removing excess hydrogen

Volatility surprises arise in removing excess hydrogen
Simulated crystal structures of virgin-DEB and T4H-DEB (chemically known as 1,4-distyrylbenzene, a trans-isomer of DEB intermediate product after the capture of first 4 atomic hydrogen with 2 CH bonds on opposing sides of the carbon chain). The top left and top right structures correspond to side view and top view of virgin DEB, respectively. The middle right, bottom right and bottom left structures correspond to side view, top view and a unit cell (side view) of T4H-DEB, respectively. Credit: The simulation was performed by Hom Sharma. Artistic rendering of the image was done by Alexandria Holmberg Diaz, Lawrence Livermore National Laboratory.

Excess hydrogen can cause problems in a variety of industries. It can corrode semiconductors, electronics, and nuclear fuel sitting in storage. It also poses an explosion hazard. To remove this extra hydrogen, chemists can use an organic compound called a hydrogen getter that chemically binds to several hydrogen atoms.

But sometimes, during this binding process—called catalytic hydrogenation—the partially hydrogenated products become volatile, melting and evaporating away before they can bind to more . Now, researchers have explored how and why this volatility varies during hydrogenation, suggesting that a previously underappreciated effect from carbon-hydrogen bonds in the molecule is the main culprit.

The new analysis, published in The Journal of Chemical Physics, can help chemists identify the ideal conditions needed for catalytic hydrogenation so they can better remove excess hydrogen.

"This creates a model for the behavior of other organic getters, allowing us to predict their optimal operating temperatures and environments," said Long Dinh, a physicist at Lawrence Livermore National Laboratory.

Dinh and his colleagues focused on a getter called 1,4 bis(phenylethynyl)benzene, or DEB. To remove hydrogen, crystal flakes of DEB are mixed with catalysts in the form of solid pellets. The pellets are made from activated carbon—whose porous structure provides abundant surface area—coated with palladium nanoparticles. The palladium catalyst splits hydrogen molecules into hydrogen atoms, which can then bind to DEB and form carbon-hydrogen bonds.

DEB is a high-capacity getter, capable of binding with up to eight hydrogen atoms. Most researchers thought that as getters like DEB bind with more hydrogen atoms and enlarge, they become more volatile. At high operating temperatures, they can then vaporize away, drifting far from the catalytic pellets where there aren't any hydrogen atoms with which to bind. "You stop the hydrogenation process prematurely," Dinh said.

But the researchers found that in the first two steps of hydrogenation, when DEB forms two carbon-hydrogen bonds per step (the carbon-hydrogen bonds are created on opposite sides of the molecule's carbon chain), the molecule actually decreases in volatility. Only in subsequent steps of hydrogenation does DEB become more volatile.

To study how and why DEB changes in volatility, the researchers measured properties such as vapor pressures and melting points, probed molecular structure, and ran quantum mechanical computer simulations to model the hydrogenation process. Their analysis suggests that the carbon-hydrogen bonds in DEB play a key role in the molecule's volatile behavior.

During hydrogenation, hydrogen binds to carbon in DEB. According to conventional thought, the resulting carbon-hydrogen is nonpolar—neither end of the barbell structure is more negatively or positively charged than the other. But it turns out that the carbon end is slightly more negative, and the carbon-hydrogen bond forms a weak dipole, Dinh explained.

As a dipole, a carbon-hydrogen bond can attract or repel other carbon-hydrogen bonds in other DEB molecules. Depending on how the carbon-hydrogen bonds are arranged and how many there are in the intermediate DEB products, the molecules can either attract or repel one another, and thus be less or more volatile, respectively. Previous research had overlooked these collective interactions among in organic crystals, Dinh said.

From their analysis, the researchers determined that the optimal conditions for DEB is below about 175 degrees Fahrenheit, if done in a good vacuum. "Our results," Dinh said, "can be applied analogously to other catalytic organic hydrogen getter systems as well."


Explore further

Green functionalisation of carbon-hydrogen bonds

More information: "Volatility of the catalytic hydrogenation products of 1,4 bis(phenylethynyl)benzene," Journal of Chemical Physics (2017). DOI: 10.1063/1.5001205
Journal information: Journal of Chemical Physics

Citation: Volatility surprises arise in removing excess hydrogen (2017, November 15) retrieved 26 May 2020 from https://phys.org/news/2017-11-volatility-excess-hydrogen.html
This document is subject to copyright. Apart from any fair dealing for the purpose of private study or research, no part may be reproduced without the written permission. The content is provided for information purposes only.
68 shares

Feedback to editors

User comments