Plasmonics could bring sustainable society, desalination tech

Plasmonics could bring sustainable society, desalination tech
Plasmonics could bring advances in chemical manufacturing, usher in new clean and sustainable technologies and desalination systems to avert a future global water crisis. Credit: Purdue University file image/Alberto Naldoni

The emerging field of plasmonics could bring advances in chemical manufacturing, usher in new clean and sustainable technologies and desalination systems to avert a future global water crisis.

Plasmonic materials contain features, patterns or elements that enable unprecedented control of light by harnessing clouds of electrons called surface plasmons.

"Plasmonics offers the ultimate control over light and photochemistry, with the help of metallic nanostructures capable of concentrating electromagnetic energy into nanoscale volumes," said Vladimir M. Shalaev, Purdue University's Bob and Anne Burnett Distinguished Professor in Electrical and Computer Engineering. "It may have a transformative impact on the way we will drive, manipulate, enhance, and monitor processes in the future."

The potential for practical applications is discussed in a commentary to appear on Friday (June 2) in the Perspectives section of Science magazine. The article was written by visiting scientist Alberto Naldoni; Shalaev; and Mark Brongersma, a professor in the Department of Materials Science and Engineering at Stanford University.

Surface plasmons and "resonant nanostructures" might be harnessed for the ultra-efficient manufacture of chemicals and fuels. One example is the potential use of these nanostructures combined with semiconductor devices that harvest light to perform catalysis.

When semiconductors are illuminated, electrons are said to be "excited," moving from one energy level, or band, to another and leaving behind "holes." Surface plasmons are groups of electrons that collectively become excited and then "decay," or lose energy, re-emitting photons or highly energetic, "hot," electrons and holes. These can be used to drive chemical reactions.

Innovations in plasmonics could make it possible to explore new types of chemistry that are typically only possible at high temperatures and pressures. The cause "local heating," which holds promise for applications such as chemical separation and distillation for industrial processes, and saltwater desalination.

"The world is facing a freshwater crisis, and cheap, efficient production of freshwater from saltwater would mean an end to this global challenge," Shalaev said. "Plasmonic nanoparticles can be self-assembled inside the nanochannels of a membrane that floats on water. Upon irradiation, the device absorbs more than 96 percent of the solar spectrum and focuses the absorbed energy in nanoscale water volumes, enabling steam generation and efficient desalination."

Plasmonics also might be combined with DNA to produce custom-made "three-dimensional metamolecules" and light-driven molecular robots for applications in chemistry, technology and medicine.

"Such plasmonic machines could be implemented for carrying out smart operations such as transport of molecules and information processing," he said.

Scaling up plasmonic chemistry to the industrial level would require development of new alternative plasmonic materials, the use of "metasurfaces" and flexible nanophotonic platforms.

"The transition to a clean and sustainable society is already taking place," Shalaev said. "Plasmonics can help accelerate this changeover by enabling, manipulating, enhancing, and monitoring with atomic-scale precision and control."

Explore further

In plasmonics, 'optical losses' could bring practical gain

More information: Applying plasmonics to a sustainable future, Science  02 Jun 2017: Vol. 356, Issue 6341, pp. 908-909, DOI: 10.1126/science.aan5802 ,
Journal information: Science

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Jun 02, 2017
It's not "sustainable societies" or water that limits or creates a sustainable population - its energy and economically feasible sources of bioactive phosphorus that are the primary bottlenecks to sustainability. Even plasmonics require substantial energy and finite material inputs. Currently, we are only approaching 4-7X times sustainable populations based on current finite critical resource material sourcing, processing and or recycling technology and associated economics. Like all animal populations - we're going back to population numbers that can be sustained by critical finite resources of this planet - or spread to other planets and use their resources.

Jun 03, 2017
By industrially wasting our sustainable *natural* clean water systems, we will transfer our dependence on clean water to *industrial* clean water systems. So the owners of the cleaning property can get paid by everyone every time around the cycle.

That these owners also own the industrial systems polluting the natural clean water is a "funny" coincidence.

Jun 04, 2017
N. America has no water problem. They have more freshwater than anywhere else on the planet. It just needs correct distribution. Other places on Earth have ruined their water systems and they should be working harder to develop things like retrieving water from Antarctica, things like that. If the global warming kooks are right, it might all melt away. Seems a waste.

Jun 04, 2017
N. America

"Just needs correct distribution" is a problem. Especially in the West, where some of the planet's biggest engineering projects have exhausted some of the planet's biggest rivers and aquifers, even as population, agriculture and industry grow past those limits.

The US (with Canada's help) has done all it can to pollute the Great Lakes, and was cleaning it up until Trump cancelled that in his budget last month. The entire region is headed to Flint's brain damage.

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