A new spin on electronics: Study discovers a 'miracle material' for field of spintronics

May 29, 2017
A schematic of the ultrafast optics experiment. An initial laser pulse aligns an electron spin along the beam path; the electron spin precesses in an external magnetic field; another time delayed laser pulse detects the spin precession by rotation of its polarization plane (North or Up, South or Down). Upper left: the material structure of the hybrid perovskites. Lower right: typical data shows oscillations induced by spin precession. Credit: Patrick Odenthal

A University of Utah-led team has discovered that a class of "miracle materials" called organic-inorganic hybrid perovskites could be a game changer for future spintronic devices.

Spintronics uses the direction of the electron —either up or down—to carry information in ones and zeros. A device can process exponentially more data than traditional electronics that use the ebb and flow of electrical current to generate digital instructions. But physicists have struggled to make a reality.

The new study, published online today in Nature Physics, is the first to show that organic-inorganic hybrid perovskites are a promising material class for spintronics. The researchers discovered that the perovskites possess two contradictory properties necessary to make spintronic devices work—the electrons' spin can be easily controlled, and can also maintain the spin direction long enough to transport information, a property known as spin lifetime.

"It's a device that people always wanted to make, but there are big challenges in finding a material that can be manipulated and, at the same time, have a long spin lifetime," says Sarah Li, assistant professor in the Department of Physics & Astronomy at the U and lead author of the study. "But for this material, it's the property of the material itself that satisfies both."

The miracle material

Organic-inorganic hybrid perovskites is already famous in scientific circles for being amazingly efficient at converting sunlight into electricity.

"It's unbelievable. A miracle material," says Z. Valy Vardeny, distinguished professor in the Department of Physics & Astronomy and co-author of the study, whose lab studies solar cells. "In just a few years, solar cells based on this material are at 22 percent efficiency. And now it has this spin lifetime property. It's fantastic."

The material's chemical composition is an unlikely candidate for spintronics, however. The hybrid perovskite inorganic frame is made of heavy elements. The heavier the atom, the easier it is to manipulate the electron spin. That's good for spintronics. But other forces also influence the spin. When the atoms are heavy, you assume the spin lifetime is short, explains Li.

"Most people in the field would not think that this material has a long spin lifetime. It's surprising to us, too," says Li. "We haven't found out the exact reason yet. But it's likely some intrinsic, magical property of the material itself."

Sarah Li (left) and Z. Valy Vardeny (right) of the Department of Physics & Astronomy at the University of Utah discuss the ultrafast laser used to prepare and measure the direction of the electron spin of hybrid perovskite methyl-ammonium lead iodine (CH3NH3PbI3). They are the first to show that organic-inorganic hybrid perovskites are a promising material class for spintronics, an emerging field that uses the spin of the electron to carry information, rather than the electronic charge used in traditional electronics. Credit: University of Utah

Spintronics: That magnetic moment when...

Cellphones, computers and other electronics have silicon transistors that control the flow of electrical currents like tiny dams. As devices get more compact, transistors must handle the electrical current in smaller and smaller areas.

"The silicon technology, based only on the electron charge, is reaching its size-limit," says Li, "The size of the wire is already small. If gets any smaller, it's not going to work in a classical way that you think of."

"People were thinking, 'How do we increase the amount of information in such a small area?'" adds Vardeny. "What do we do to overcome this limit?"

"Spintronics," answers physics.

Spintronics uses the spin of the electron itself to carry information. Electrons are basically tiny magnets orbiting the nucleus of an element. Just like the Earth has its own orientation relative to the sun, electrons have their own spin orientation relative to the nucleus that can be aligned in two directions: "Up," which represents a one, and "down," which represents a zero. Physicists relate the electron's "magnetic moment" to its spin.

By adding spin to traditional electronics, you can process exponentially more information than using them classically based on less or more charge.

"With spintronics, not only have you enormously more information, but you're not limited by the size of the transistor. The limit in size will be the size of the magnetic moment that you can detect, which is much smaller than the size of the transistor nowadays," says Vardeny.

The ultrafast laser shoots very short light pulses 80 million times a second at the hybrid perovskite material to determine whether its electrons could be used to carry information in future devices. They split the laser into two beams; the first one hits the film to set the electron spin in the desired direction. The second beam bends through a series of mirrors like a pin ball machine before hitting the perovskite film at increasing time intervals to measure how long the electron held the spin in the prepared direction. Credit: University of Utah

The experiment to tune electron spin

Tuning an electron spin is like tuning a guitar, but with a laser and a lot of mirrors.

First, the researchers formed a thin film from the hybrid perovskite methyl-ammonium lead iodine (CH3NH3PbI3) and placed it in front of an ultrafast laser that shoots very short light pulses 80 million times a second. The researchers are the first to use light to set the electron's spin orientation and observe the spin precession in this material.

They split the laser into two beams; the first one hit the film to set the in the desired direction. The second beam bends through a series of mirrors like a pinball machine before hitting the perovskite film at increasing time intervals to measure how long the electron held the spin in the prepared direction.

They found that the perovskite has a surprisingly long spin lifetime—up to nanosecond. The spin flips many times during one nanosecond, which means a lot information can be easily stored and manipulated during that time.

Once they determined the long spin lifetime, the researchers tested how well they could manipulate the spin with a magnetic field.

"The spin is like the compass. The compass spins in this magnetic field perpendicular to that compass, and eventually it will stop spinning," says Li. "Say you set the spin to 'up,' and you call that 'one.' When you expose it to the magnetic field, the spin changes direction. If it rotated 180 degrees, it changes from one to zero. If it rotated 360 degrees, it goes from one to one."

They found that they could rotate the spin more than 10 turns by exposing the electron to different strengths of .

The potential for this material is enormous, says Vardeny. It could process data faster and increase random-access memory.

"I'm telling you, it's a miracle material," says Vardeny.

Explore further: Report sheds new insights on the spin dynamics of a material candidate for low-power devices

More information: Spin-polarized exciton quantum beating in hybrid organic–inorganic perovskites, Nature Physics (2017). nature.com/articles/doi:10.1038/nphys4145

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trevor_white
not rated yet May 29, 2017
Magic? it is far more likely that the combination creates a bound stable state, which will lengthen it's half life.
Benni
5 / 5 (1) May 30, 2017
This website continually complains about my using an ad blocker. Well When this site realises THAT I HAVE DATA CAPS AND THE AD USE UP MY DATA


Yep, Physorg is simply complaining about YOUR refusal to pay for the costs of the ads they insist on shoving in our faces. The automatic startup videos are the worst ones when it comes to eating into the datacap limitation that you're paying $50-100/month for.

If Physorg thinks their ads are so damn relevant to what we're reading, then they should be a stand alone feature & we can decide for ourselves if they are relevant. A long time ago I got tired of coming here & having drop down ads follow me around from some site trying to sell me bluejeans, and they would drop those ads right down into the middle of the most intense part of the reading of the article, either that or there would be an immediate startup video from some online healthfood joint. This is not the FREE internet service Physorg claims their site is.

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