Single-angle ptychography allows 3-D imaging of stressed materials

Single-angle ptychography allows 3-D imaging of stressed materials
Scientists have used a new X-ray diffraction technique called Bragg single-angle ptychography to get a clear picture of how planes of atoms shift and squeeze under stress. Credit: Robert Horn/Argonne National Laboratory

Everyone reacts differently under stress—even the relatively orderly atoms in a crystal. If scientists could get a clear picture of how planes of atoms shift and squeeze under stress, they could make use of those properties to provide emerging technologies, like nanoelectronics and next-generation semiconductor components, with extra speed or functionalities. However, creating this picture requires new techniques for imaging atoms in materials and their behavior in different environments.

In a recent collaborative study from the Institut Fresnel, IBM and the U.S. Department of Energy's (DOE) Argonne National Laboratory, scientists developed a new form of imaging that uses X-ray diffraction patterns, called single-angle Bragg ptychography.

Although Bragg ptychography and especially X-ray diffraction have been around for a while, single-angle Bragg ptychography allows for easier reconstruction of 3-D data about how strain affects a material.

In X-ray diffraction, the atoms within a material "scatter" the incoming X-rays, producing a signal on a detector. Because there are so many overlapping diffraction events happening simultaneously, it can be hard to identify the contribution of a particular small region of the lattice to the overall signal. To compensate for this, scientists use a method called Fourier analysis, which essentially converts the overall signal to a series of waves with peaks and valleys that correspond to the relative intensities of various parts of the signal.

However, just doing regular X-ray diffraction only tells part of the story, said lead author and Argonne scientist Stephan Hruszkewycz. "In order to really see and understand the strain in real space, you need on both intensity and the phase," he said. "What we needed was a trick to retrieve the missing phases of the diffraction pattern."

Phase can be understood by imagining waves lapping onto the shore after someone throws a handful of rocks into a still pond. Measuring the height of waves at the shore as well as their arrival time could allow you to "watch the wave backwards" by reconstructing the positions and sizes of all the rocks when they hit the water. X-ray detectors, however, only measure the height of the waves; phases, i.e. when the wave reaches the shore, must be recovered by other means.

The trick the authors used comes from ptychography, a technique that is able to recover phase information by using redundant sampling from the same region of the crystal. By shifting the X-ray beam only slightly, and by imaging as much as 60 percent of the same real space between beam positions, the team was able to extract information about the phase.

"In essence, by having a lot of the same information encoded in neighboring samples, it constrains the possible configurations of the crystal in ," Hruszkewycz said.

The real advance, however, came not from information gathered through diffraction, but from the positioning of the beam itself. Because the researchers knew exactly where the beam was positioned and the angle at which the crystal's atomic planes would scatter the X-rays, they were able to extract additional information about how the strain affected the material in three dimensions.

"Most techniques, including some ptychographic ones, really only give a 2-D representation of the sample of interest," Hruszkewycz said. "This technique also makes fewer requirements in terms of the instrument technology than comparable techniques for generating 3-D information about materials."

An article based on the study, "High-resolution three-dimensional structural microscopy by single-angle Bragg ptychography," appeared in November in the online edition of Nature Materials.

Explore further

Turning up the heat for perfect (nano)diamonds

More information: S. O. Hruszkewycz et al. High-resolution three-dimensional structural microscopy by single-angle Bragg ptychography, Nature Materials (2016). DOI: 10.1038/nmat4798
Journal information: Nature Materials

Citation: Single-angle ptychography allows 3-D imaging of stressed materials (2017, March 22) retrieved 15 January 2021 from
This document is subject to copyright. Apart from any fair dealing for the purpose of private study or research, no part may be reproduced without the written permission. The content is provided for information purposes only.

Feedback to editors

User comments