Graphene balloons show their colors

November 7, 2016
Artist's impression of graphene balloons showing colors. Under large deformations, Newton rings appear. Credit: Delft University of Technology

Researchers from the Graphene Flagship have found a new potential application for graphene: mechanical pixels. By applying a pressure difference across graphene membranes, the perceived color of the graphene can be shifted continuously from red to blue. This effect could be exploited for use as colored pixels in e-readers and other low-powered screens. The research was a collaborative effort from researchers at TU Delft, Netherlands, and Graphenea, Spain, and the study has recently been published in the journal Nano Letters.

In graphene balloon devices, a double layer of graphene two atoms thick is deposited on top of circular indents cut into silicon. The graphene membranes enclose air inside the cavities, and the position of the membranes can be changed by applying a between the inside and the outside. When the membranes are closer to the silicon they appear blue; when the membranes are pushed away they appear red.

The color change effect arises from interference between light waves reflected from the bottom of the cavity and the membrane on top. These reflected waves interfere constructively or destructively depending on the position of the membrane – either adding up or cancelling out different parts of the spectrum of white light. This interference enhances or reduces certain colors in the reflected light.

Dr. Samer Houri, a researcher at TU Delft, led the exiting work. "At the beginning, we did not pay attention to the colors of the membranes because graphene is 'colorless' when isolated. However, we observed Newton rings and noticed their color changing over time," he said. When the membranes are extremely deformed, their color is no longer homogeneous, but instead circular rings appear. These rings are called Newton rings in honor of Sir Isaac Newton, who studied them in 1717.

Credit: Ana Cartamil

Santiago Cartamil-Bueno is a Ph.D. student at TU Delft, who carried out the experimental work and was first to observe the change in color. "Not only does this provide the colorimetry technique for characterizing suspended graphene, which is useful for companies developing graphene mechanical sensors, but it also provides a means to implement display technology based on interferometry modulation," says Cartamil-Bueno. Interferometry modulation, or IMOD, is employed in displays that have low-power consumption requirements, such as smart watches and e-books, and is increasing in importance for Internet of Things devices. Currently, such displays are composed of mechanical pixels made of silicon materials. "By instead using graphene, with its extraordinary mechanical properties," Cartamil-Bueno says, "a GIMOD (Graphene IMOD) could drastically improve the device performance –power consumption, pixel response time, failure rates, etc.– while enabling electrical integration and even flexible devices." The researchers are now working to control the color of the membranes with electricity, and hope to have a screen prototype for the Mobile World Conference 2017 in Barcelona.

Explore further: New study shows nickel graphene can be tuned for optimal fracture strength

More information: Santiago J. Cartamil-Bueno et al, Colorimetry Technique for Scalable Characterization of Suspended Graphene, Nano Letters (2016). DOI: 10.1021/acs.nanolett.6b02416

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