Working under pressure: Diamond micro-anvils will produce immense pressures to make new materials

Working under pressure: Diamond micro-anvils with huge pressures will create new materials
Yogesh Vohra. Credit: UAB

University of Alabama at Birmingham researchers will use pressures greater than those found at the center of the Earth to potentially create as yet unknown new materials. In the natural world, such immense forces deep underground can turn carbon into diamonds, or volcanic ash into slate.

The ability to produce these pressures depends on tiny nanocrystalline-diamond anvils built in a UAB clean room manufacturing facility. Each anvil head is just half the width of an average human hair. The limits of their pressure have not yet been reached as the first 27 prototypes are being tested.

"We have achieved 75 percent of the pressure found at the center of the Earth, or 264 gigapascals, using lab-grown nanocrystalline-diamond micro-anvil," said Yogesh Vohra, Ph.D., a professor and university scholar of physics in the UAB College of Arts and Sciences. "But the goal is one terapascal, which is the pressure close to the center of Saturn. We are one-quarter of the way there."

One terapascal, a scientific measure of pressure, is equal to 147 million pounds per square inch.

One key to is to make the point of the anvil, where the pressure is applied, very narrow. This magnifies the pressure applied by a piston above the micro-anvil, much like the difference of being stepped on by a spiked high heel rather than a loafer.

A more difficult task is how to make an anvil that is able to survive this ultra-high pressure. The solution for the Vohra team is to grow a nanocrystalline pillar of diamond—30 micrometers wide and 15 micrometers tall—on the culet of a gem diamond. The culet is the flat surface at the bottom of a gemstone.

Working under pressure: Diamond micro-anvils will produce immense pressures to make new materials
This nubbin on the flat surface of a gem diamond (top) is a nanocrystalline diamond, half the width of an average human hair. Higher magnification (bottom) shows the granular structure of the nanocrystalline diamond. Credit: University of Alabama at Birmingham
"We didn't know that we could grow nanocrystalline diamonds on a diamond base," Vohra said. "This has never been done before."

In the 264-gigapascal pressure test at Argonne National Laboratory in Lemont, Illinois, the nanocrystalline diamond showed no sign of deformation. Vohra and colleagues recently reported this result in the American Institute of Physics journal AIP Advances.

"The structure did not collapse when we applied pressure," Vohra said. "Nanocrystalline diamond has better mechanical properties than gem diamonds. The very small-sized grain structure makes it really tough."

As more micro-anvils are tested and improved, they will be used to study how transition metals, alloys and rare earth metals behave under extreme conditions. Just as graphitic carbon that is subjected to high pressure and temperature can turn into diamond, some materials squeezed by the micro-anvils may gain novel crystal modifications with enhanced physical and mechanical properties—modifications that are retained when the pressure is released. Such new materials have potential applications in the aerospace, biomedical and nuclear industries.

The micro-anvils are made in a Class 7000 clean room in the UAB Diamond Microfabrication Lab, using maskless lithography and microwave plasma chemical vapor deposition.

Vohra says his research team wants to generate smaller grain sizes in the nanocrystalline diamond, which may make it even stronger; understand how the nanocrystalline diamond is bonded to the gem diamond; and use ion beams to machine the top of the micro-anvil to a hemispherical shape. That shape will mean an even narrower contact point, thus increasing the pressure.

Testing is done at Argonne because it has a very bright synchrotron X-ray source that can probe crystal structure of micron-sized materials under . Vohra and two graduate students travel to Argonne about four times a year.

Explore further

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More information: Gopi K. Samudrala et al, Nanocrystalline diamond micro-anvil grown on single crystal diamond as a generator of ultra-high pressures, AIP Advances (2016). DOI: 10.1063/1.4964299
Journal information: AIP Advances

Citation: Working under pressure: Diamond micro-anvils will produce immense pressures to make new materials (2016, October 18) retrieved 25 June 2019 from
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Oct 18, 2016
Stupid (maybe) question... when applying pressure with this anvil, wouldn't most material squeeze out the edge? Maybe you only need the tiny piece of material left under the anvil to prove the theory?

I guess it would be hard to use an "inverted cup" type design that pushes down on to a surface with a ring cut out of it, such that the edges of the cup keep stuff from squeezing out, while the ring still lets the edges of the cup through so the material inside is all pressurised. I guess it would be hard/impossible to keep the material from squeezing in to the gap between the cup and the ring anyway... and maybe doesn't offer any benefit other than having "more stuff" compared to what would be trapped under this anvil...

Oct 18, 2016
Typically, normal diamond anvils are gasketed in some fashion. The rounded anvil idea is interesting and maybe some force will allow a small amount of to remain in the pressure zone, but I see it as more of a research effort, rather than a production device of any kind. Interesting work.

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