For more than a century and a half of physics, the Second Law of Thermodynamics, which states that entropy always increases, has been as close to inviolable as any law we know. In this universe, chaos reigns supreme.

But researchers with the U.S. Department of Energy's (DOE's) Argonne National Laboratory announced recently that they may have discovered a little loophole in this famous maxim.

Their research, published in *Scientific Reports*, lays out a possible avenue to a situation where the Second Law is violated on the microscopic level.

The Second Law is underpinned by what is called the *H*-theorem, which says that if you open a door between two rooms, one hot and one cold, they will eventually settle into lukewarm equilibrium; the hot room will never end up hotter.

But even in the twentieth century, as our knowledge of quantum mechanics advanced, we didn't fully understand the fundamental physical origins of the *H*-theorem.

Recent advancements in a field called quantum information theory offered a mathematical construction in which entropy increases.

"What we did was formulate how these beautiful abstract mathematical theories could be connected to our crude reality," said Valerii Vinokur, an Argonne Distinguished Fellow and corresponding author on the study.

The scientists took quantum information theory, which is based on abstract mathematical systems, and applied it to condensed matter physics, a well-explored field with many known laws and experiments.

"This allowed us to formulate the quantum *H*-theorem as it related to things that could be physically observed," said Ivan Sadovskyy, a joint appointee with Argonne's Materials Science Division and the Computation Institute and another author on the paper. "It establishes a connection between well-documented quantum physics processes and the theoretical quantum channels that make up quantum information theory."

The work predicts certain conditions under which the *H*-theorem might be violated and entropy—in the short term—might actually decrease.

As far back as 1867, physicist James Clerk Maxwell described a hypothetical way to violate the Second Law: if a small theoretical being sat at the door between the hot and cold rooms and only let through particles traveling at a certain speed. This theoretical imp is called "Maxwell's demon."

"Although the violation is only on the local scale, the implications are far-reaching," Vinokur said. "This provides us a platform for the practical realization of a quantum Maxwell's demon, which could make possible a local quantum perpetual motion machine."

For example, he said, the principle could be designed into a "refrigerator" which could be cooled remotely—that is, the energy expended to cool it could take place anywhere.

The authors are planning to work closely with a team of experimentalists to design a proof-of-concept system, they said.

The study, "H-theorem in quantum physics," was published September 12 in *Nature Scientific Reports*.

**Explore further:**
Small entropy changes allow quantum measurements to be nearly reversed

**More information:**
G. B. Lesovik et al, H-theorem in quantum physics, *Scientific Reports* (2016). DOI: 10.1038/srep32815

## Andrew Palfreyman

## BackBurner

Experimentalists?

## phi-stee

That's right, it's a word, take the opportunity to increase your vocabulary.

## manfredparticleboard

## Anonym

## KBK

Thus the 'second law'. But it can be violated, it involves resonance manipulation and then gating the energies of the firmament. There are many stories of such methodologies being used to enable Maxwell's demon. Complex accelerations in resonance being used as coupling devices to affect time and mass changes, to 'diode pump' the energies involved.

There are many examples to peruse, if one steps out of their textbook analysis. Which is obvious as requirements go. The dogmatic canon of 'second law' requires investigation outside of the canon, as the canon locks the door in a logic loop.

It's a simple point in straightforward logic if one steps outside of the mainstream. The problem is human, not one of logic or analysis.

## ExNuke

## optical

Oct 23, 2016## optical

Oct 23, 2016## Lex Talonis

Yah - they are sidekick.

## swordsman

## antialias_physorg

Could you be a tad more unspecific, please.

/s

## luke_w_bradley

I have seen a perpetual motion fountain, made out of superfluid helium.

https://www.youtu...#t=1m28s

It emerges from the macro scale quantum effects in this material, and can only last as long as its cooled to that point, but its pretty interesting that we're not barred from breaking these other laws if we stack the quantum deck in the right way.

## TheGhostofOtto1923

http://webcast.ma...8f26811d

-And I'm required to add that neither physorg nor otto in any endorse this presentation just by causing it to be viewed by the world. But I think we both can say it's pretty provocative and it does mention thermodynamics.