Chemists tackle battery overcharge problem

Chemists tackle battery overcharge problem

Research from the University of Kentucky Department of Chemistry will help batteries resist overcharging, improving the safety of electronics from cell phones to airplanes.

The research, led by Susan Odom's group, has focused on the design, synthesis, and testing of that can be incorporated into the electrolytes of to improve their safety profiles. Specifically, Odom's team is studying compounds called redox shuttles.

Lithium-ion batteries are the energy storage technology of choice for portable consumer electronic devices such as laptops and cell phones. Over the past few years, these batteries have been incorporated on larger scales into and airplanes. Battery safety is of utmost importance to manufacturers and consumers, especially in applications where failure can result in the loss of lives.

Overcharge is a serious concern for batteries connected in series. It can lead to catastrophic failures in the form of fires and explosions. The redox shuttle compounds being studied at UK prevent overcharge by transporting electrons between battery electrodes when excessive current is applied to fully charged batteries.

Members of the Odom group, including undergraduate researcher Corrine "Nina" Elliott, designed a new phenothiazine derivative that protects batteries from overcharging for thousands of hours. The protection offered by this compound, 3,7-bis(trifluoromethyl)phenothiazine, lasted more than four times longer than the only commercial competitior.

The Odom group plans to test the performance of this redox shuttle in larger batteries, similar to those that are being used in electric vehicles.

More information: "3,7-Bis(trifluoromethyl)-N-ethylphenothiazine: a redox shuttle with extensive overcharge protection in lithium-ion batteries." J. Mater. Chem. A, 2014,2, 18190-18193. DOI: 10.1039/C4TA04463K

Journal information: Journal of Materials Chemistry A

Citation: Chemists tackle battery overcharge problem (2014, October 17) retrieved 15 June 2024 from
This document is subject to copyright. Apart from any fair dealing for the purpose of private study or research, no part may be reproduced without the written permission. The content is provided for information purposes only.

Explore further

Toward making lithium-sulfur batteries a commercial reality for a bigger energy punch


Feedback to editors