'White graphene' halts rust in high temps

October 7, 2013 by Mike Williams, Rice University

Rice University researchers have discovered that sheets of hexagonal boron nitride (h-BN) as little as one atom thick can protect metals in harsh environments at up to 1,100 degrees Celsius. The top image shows uncoated nickel oxidized after exposure to high temperature in an oxygen-rich environment. The second shows nickel exposed to the same conditions with a 5-nanometer coat of h-BN. The third shows electron microscope images of two, three, four and many-layer h-BN films. The bottom image of an h-BN sheet shows the hexagonal arrangement of nitrogen (bright) and boron atoms. Credit: Zheng Liu
(Phys.org) —Atomically thin sheets of hexagonal boron nitride (h-BN) have the handy benefit of protecting what's underneath from oxidizing even at very high temperatures, Rice University researchers have discovered.

One or several layers of the material sometimes called "white graphene" keep materials from oxidizing – or rusting—up to 1,100 degrees Celsius (2,012 degrees Fahrenheit), and can be made large enough for industrial applications, they said.

The Rice study led by materials scientists Pulickel Ajayan and Jun Lou appears in the online journal Nature Communications.

Oxidation prevention is already big business, but no products available now work on the scale of what the Rice lab is proposing. The researchers see potential for very large sheets of h-BN only a few atoms thick made by scalable vapor deposition methods.

"We think this opens up new opportunities for two-dimensional material," said Lou, an associate professor of mechanical engineering and materials science. "Everybody has been talking about these materials for electronic or photonic devices, but if this can be realized on a large scale, it's going to cover a broad spectrum of applications."

Lou said ultrathin h-BN protection might find a place in turbines, jet engines, oil exploration or underwater or other harsh environments where minimal size and weight would be an advantage, though wear and abrasion could become an issue and optimum thicknesses need to be worked out for specific applications.

It's effectively invisible as well, which may make it useful for protecting solar cells from the elements, he said. "Essentially, this can be a very useful structural material coating," Lou said.

The researchers made small sheets of h-BN via chemical (CVD), a process they said should be scalable for industrial production. They first grew the thin material on nickel foil and found it withstood high temperature in an oxygen-rich environment. They also grew h-BN on graphene and found they could transfer sheets of h-BN to copper and steel with similar results.

"What's amazing is that these layers are ultrathin and they stand up to such ultrahigh temperatures," Ajayan said. "At a few nanometers wide, they're a totally non-invasive coating. They take almost no space at all."

Explore further: Fine patterns that combine single-atom-thick graphene, boron nitride point toward 2-D electronic devices

More information: www.nature.com/ncomms/2013/131 … full/ncomms3541.html

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not rated yet Oct 08, 2013
This could be the next-generation shielding for spacecraft ?
Wonder how good it is at stopping cosmic rays
not rated yet Oct 08, 2013
There are many industrial products that claim to have a BN coating, not not sure if it is the same.
not rated yet Oct 09, 2013
@FMA - most of the industrial coatings are cubic boron nitride (c-BN) rather than hexagonal boron nitride (h-BN).

In the periodic table boron is just to left of carbon and nitrogen is just to the right, so boron nitride behaves in some ways like carbon.

Cubic boron nitride has a similar structure to diamond (a 3D crystalline form of carbon) and extremely hard (almost as hard as diamond), hence its use as a tool coating where it prevents wear.

Hexagonal boron nitride has a similar structure to graphite (a form of carbon whose 3D form is a weakly-bonded stack of very strong 2D layers), and like graphite it is soft and used as a lubricant because the layers slide on one another.

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