The birth of a very-high-field superconductor

February 5, 2013 by Kurt Riesselmann, US Department of Energy
Fermilab scientist Tengming Shen and his collaborators have discovered how to make better superconducting wires for magnets.

The strong magnetic fields of an MRI scanner or a particle accelerator are generated efficiently by electromagnets that have superconducting wire in their coils. A group of scientists has discovered how to make better wires using a promising material known as Bi-2212. With this discovery comes the possibility of creating magnetic fields in excess of 30 Tesla, three to four times higher than those generated by present accelerator magnet technology.

Bi-2212 (Bi2Sr2CaCu2Ox) is one of the copper-oxide high-temperature superconductors discovered 27 years ago. Since then, attention has focused on the use of such HTS in electric power transmission and other electrical applications not related to high-field magnets. In those applications, Bi-2212 loses out to other HTS materials.

Yet scientists had recognized for a long time the potential of Bi-2212 for use in superconducting magnet coils. When cooled with , many HTS materials, including Bi-2212, can conduct large without resistance even in the presence of huge magnetic fields. But so far scientists only have managed to turn three of these HTS materials into the long wires that are necessary to make coils. Among these materials, Bi-2212 stands out as the only HTS that can be fabricated as a round wire. This makes Bi-2212 a perfect candidate for winding cables and coils without significantly changing present magnet technology.

Until recently, Bi-2212 wires more than a few centimeters long wouldn't carry enough electric current to make it worthwhile to consider them for magnet technology. Last month, a group of scientists—led by Tengming Shen at DOE's —announced how to beef up the electrical capacity of Bi-2212 wires. Previous studies by Shen and collaborating scientists had shown that the wire's low is due to that form during a process that melts and re-solidifies thread-like filaments of Bi-2212.

Shen and Arup Gosh, a scientist at DOE's Brookhaven Lab, now have discovered that the root cause of the problem is the high gas pressure inside the Bi-2212 wires. They observed that long-length conductors swell, crack or even bulge locally at high-temperatures due to contaminants such as air and water, which get absorbed by Bi-2212 powder, and solid remnants in powder that gasify upon heating. This explained why short pieces of Bi-2212 performed well, but long wires did not.

Together with Lance Cooley, Fermilab, and a research group led by Professors David Larbalestier and Eric Hellstrom at the National High Laboratory, they have developed a technique that prevents bubble formation almost entirely by performing the melting and re-solidification of materials under high external gas pressure. The group observed five times higher current in a long wire sample made by the new method compared to an identical sample made by the standard recipe.

Importantly, the electrical currents in the improved Bi-2212 wires were two times larger than the usual benchmarks used for the development of superconducting magnet coils.

This breakthrough signifies the birth of a new high-performance, very-high-field magnet conductor. Shen and his collaborators are optimistic that they now have the recipe for a new class of superconducting magnets that could help unlock information about chemical and biological processes, create new materials and reveal the fundamental processes of the universe.

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3.7 / 5 (3) Feb 05, 2013
it's always a matter of purity in the end. You'd think this would be a common starting point in these issues by now.
not rated yet Feb 05, 2013
"Among these materials, Bi-2212 stands out as the only HTS that can be fabricated as a round wire. This makes Bi-2212 a perfect candidate for winding cables and coils without significantly changing present magnet technology."

I've often wondered why round wires are used for windings. I believed it was a consequence of the economics of manufacturing wire. I thought that a square-crossectioned wire would allow smaller devices, not wasting so much space as happens otherwise. The greater 'stacking efficiency' of square-ness might increase current-carrying capacity. Im not a physicist (as most here have probably concluded from my so-often naive contributions) and perhaps there are mathematicly-describable reasons why round beats square. Would other members of the alloy family here possible compete for consideration if 'roundness' can be shown not to have advantage?
1 / 5 (1) Feb 06, 2013
Round and edged wires may have differnig properties (e.g. depending on the frequency of the current you send through them).
When you look at circuit boards for high frequency applications you somtimes see that the lines aren't straight or at 90° angles as in other circuit boards but rounded. Any straight line acts as an antenna at high enough frequencies (when the line length drops below half the wavelength).

But today you can buy wires with square, hexagonal, ellipsoid or half-round cross sections. It's still tricky because wire is drawn through a form when it's made. This means you're drawing a round form through a differently shaped(possibly square) hole which gives you different stresses in the corners (and hence possibly different properties. Something you really want to avoid in superconducting material)

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