Researchers discover particle which could 'cool the planet'

In a breakthrough paper published in Science, researchers from The University of Manchester, The University of Bristol and Sandia National Laboratories report the potentially revolutionary effects of Criegee biradicals.

These invisible chemical intermediates are powerful oxidisers of pollutants such as and , produced by , and can naturally clean up the atmosphere.

Although these chemical intermediates were hypothesised in the 1950s, it is only now that they have been detected. Scientists now believe that, with further research, these species could play a major role in off-setting climate change.

The detection of the Criegee biradical and measurement of how fast it reacts was made possible by a unique apparatus, designed by Sandia researchers, that uses light from a third-generation synchrotron facility, at the Lawrence Berkeley National Laboratory's Advanced .

The intense, tunable light from the synchrotron allowed researchers to discern the formation and removal of different isomeric species – molecules that contain the same atoms but arranged in different combinations.

The researchers found that the Criegee biradicals react more rapidly than first thought and will accelerate the formation of sulphate and nitrate in the atmosphere. These compounds will lead to aerosol formation and ultimately to cloud formation with the potential to cool the planet.

The formation of Criegee biradicals was first postulated by Rudolf Criegee in the 1950s. However, despite their importance, it has not been possible to directly study these important species in the laboratory.

In the last 100 years, Earth's average surface temperature increased by about 0.8 °C with about two thirds of the increase occurring over just the last three decades.

Most countries have agreed that drastic cuts in greenhouse gas emissions are required, and that future global warming should be limited to below 2.0 °C (3.6 °F).

Dr Carl Percival, Reader in Atmospheric Chemistry at The University of Manchester and one of the authors of the paper, believes there could be significant research possibilities arising from the discovery of the Criegee biradicals.

He said: "Criegee radicals have been impossible to measure until this work carried out at the Advanced Light Source. We have been able to quantify how fast Criegee radicals react for the first time.

"Our results will have a significant impact on our understanding of the oxidising capacity of the atmosphere and have wide ranging implications for and .

"The main source of these Criegee biradicals does not depend on sunlight and so these processes take place throughout the day and night."

Professor Dudley Shallcross, Professor in Atmospheric Chemistry at The University of Bristol, added: "A significant ingredient required for the production of these Criegee biradicals comes from chemicals released quite naturally by plants, so natural ecosystems could be playing a significant role in off-setting warming.'

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Citation: Researchers discover particle which could 'cool the planet' (2012, January 12) retrieved 18 July 2019 from
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Jan 12, 2012
Very interesting stuff, one of the silver bullets in the haystack if you will excuse the mixed metaphor.

Scary to think we may be about to attain a godlike status, planes will be able to control the weather. Where's it all going though? Living longer healthier lives is great, but who wants to endure the phenomenon of time for a great deal of....time...

I don't want to die but being able to control everything forever doesn't sound like my idea of a wonderful existence. Work is what made us, those first cave people had to work just to live. Now look at us....everything is backwards.

If you want to quell global warming pass laws requiring private property to be reforrested to a certain percent. Offer rewards to people to grow their own food as well as high efficiency plants like algea or whatever.

Every household should be a research lab where you work hard and then learn about what you worked on, nobody should work at wal mart..

Jan 12, 2012
These compounds will lead to aerosol formation and ultimately to cloud formation with the potential to cool the planet.
These clouds have the potential to violate the circulation of water in atmosphere as well. The more nuclei we will put into clouds, the smaller their droplets will be, the slower their coalesce into rain will occur. Very tiny droplets are transparent for infrared radiation in the same way, like pure water vapor and such clouds will not reflect the heat radiation, but absorb it even more.

The road to hell is paved with good intentions. In this particular case we could take it nearly literally.

Jan 12, 2012
In addition, the Criegee biradicals will not be probably very user friendly for troposheric and stratospheric ozone - but it's rather a detail for researchers, who are trying to keep their jobs.

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