Scientists model molecular switch

Michigan Technological University physicist Ranjit Pati and his team have developed a model to explain the mechanism behind computing's elusive Holy Grail, the single molecular switch.

If born out experimentally, his work could help explode Moore's Law and could revolutionize computing technology.

Moore's Law predicts that the number of transistors that can be economically placed on an integrated circuit will double about every two years. But by 2020, Moore's Law is expected to hit a brick wall, as manufacturing costs rise and transistors shrink beyond the reach of the laws of classical physics.

A solution lies in the fabled molecular switch. If molecules could replace the current generation of transistors, you could fit more than a trillion switches onto a centimeter-square chip. In 1999, a team of researchers at Yale University published a description of the first such switch, but scientists have been unable to replicate their discovery or explain how it worked. Now, Pati believes he and his team may have found the mechanism behind the switch.

Applying quantum physics, he and his group developed a computer model of an organometallic molecule firmly bound between two gold electrodes. Then he turned on the juice.

As the laws of physics would suggest, the current increased along with the voltage, until it rose to a miniscule 142 microamps. Then suddenly, and counterintuitively, it dropped, a mysterious phenomenon known as negative differential resistance, or NDR. Pati was astonished at what his analysis of the NDR revealed.

Up until the 142-microamp tipping point, the molecule's cloud of electrons had been whizzing about the nucleus in equilibrium, like planets orbiting the sun. But under the bombardment of the higher voltage, that steady state fell apart, and the electrons were forced into a different equilibrium, a process known as "quantum phase transition."

"I never thought this would happen," Pati said. "I was really excited to see this beautiful result."

Why is this important? A molecule that can exhibit two different phases when subjected to electric fields has promise as a switch: one phase is the "zero" and the other the "one," which form the foundation of digital electronics.

Pati is working with other scientists to test the model experimentally. His results appear in the article "Origin of Negative Differential Resistance in a Strongly Coupled Single Molecule-metal Junction Device," published June 16 in Physical Review Letters.

Source: Michigan Technological University

Citation: Scientists model molecular switch (2008, June 16) retrieved 18 August 2019 from
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Jun 17, 2008
This has been the issue with molecular electronics for years. So many theorists producing calculations and simulations that sound great but don't actually follow from first principles. This really looks like an expansion of the Stark Effect which is molecular broadening due to an applied electric field. It has been analyzed for years now; nothing new.

The other real issue is: What does one do with a two terminal device? There were numerous articles in the late '90s and early '00s that showed neat features of break-junction devices done with scanning tunneling microscopes. Using an STM-based experiment as example of working devices is just absurd. Setting aside the oddity of using two-terminal NDR devices, how does one make both contacts at a production level? Typical semiconductor fabs have fewer than 1 in 10^12 bad devices and sometimes much better. Creating a gold-thiol bond to both ends of a single molecule on chip is nowhere near practical.

One last aside, NDR may be neat but it has been analyzed heavily by groups out of Purdue, Duke, and even HP. Lots of stalling for time and money and no real molecular devices. The infamous crossbar-latch was an idea whose usefulness was limited due to the inability to get quality NDR (that is: low magnitude of change vs expected value) and the low numbers of working devices (record: 35%, NOT >99.99999999). Even a working 'device' with large scale NDR may not be of that much use.

Jun 17, 2008
If they use multiferroics can make a
non-volatile molecular switch.

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